The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Self-Assembled Metal Colloid Monolayers: An Approach to SERS Substrates
Abstract
The self-assembly of monodisperse gold and silver colloid particles into monolayers on polymer-coated substrates yields macroscopic surfaces that are highly active for surface-enhanced Raman scattering (SERS). Particles are bound to the substrate through multiple bonds between the colloidal metal and functional groups on the polymer such as cyanide (CN), amine (NH 2 ), and thiol (SH). Surface evolution, which can be followed in real time by ultraviolet-visible spectroscopy and SERS, can be controlled to yield high reproducibility on both the nanometer and the centimeter scales. On conducting substrates, colloid monolayers are electrochemically addressable and behave like a collection of closely spaced microelectrodes. These favorable properties and the ease of monolayer construction suggest a widespread use for metal colloid-based substrates.
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Citations
Cites
Surface raman spectroelectrochemistry
Jeanmaire, D. L., & Van Duyne, R. P. (1977) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(77)80224-6 · Cited by 4,738
Cited by
Drying-Mediated Self-Assembly of Nanoparticles
Rabani, E., Reichman, D. R., Geissler, P. L., & Brus, L. E. (2003) · Nature · doi:10.1038/nature02087 · Cited by 913
Machine Learning Protocol for Surface-Enhanced Raman Spectroscopy
Hu, W., Ye, S., Zhang, Y., Li, T., Zhang, G., Luo, Y., Mukamel, S., & Jiang, J. (2019) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.9b02517 · Cited by 92
Metadata
- Authors
- Freeman, R. G., Grabar, K. C., Allison, K. J., Bright, R. M., Davis, J. A., Guthrie, A. P., Hommer, M. B., Jackson, M. A., Smith, P. C., Walter, D. G., & Natan, M. J.
- Venue
- Science
- Published
- 1995-03-17
- Volume
- 267
- Issue
- 5204
- Pages
- 1629-1632
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1616665557
- Cited by
- 1,289
- References
- 1
- FWCI
- 17.49
- Type
- journal article
- Language
- en
- Open access
- closed
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