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Solution-Liquid-Solid Growth of Crystalline III-V Semiconductors: An Analogy to Vapor-Liquid-Solid Growth
Abstract
Until now, micrometer-scale or larger crystals of the III-V semiconductors have not been grown at low temperatures for lack of suitable crystallization mechanisms for highly covalent nonmolecular solids. A solution-liquid-solid mechanism for the growth of InP, InAs, and GaAs is described that uses simple, low-temperature (≤203°C), solution-phase reactions. The materials are produced as polycrystalline fibers or near-single-crystal whiskers having widths of 10 to 150 nanometers and lengths of up to several micrometers. This mechanism shows that processes analogous to vapor-liquid-solid growth can operate at low temperatures; similar synthesis routes for other covalent solids may be possible.
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Cited by
One‐Dimensional Nanostructures: Synthesis, Characterization, and Applications
Xia, Y., Yang, P., Sun, Y., Wu, Y., Mayers, B., Gates, B., Yin, Y., Kim, F., & Yan, H. (2003) · Advanced Materials · doi:10.1002/adma.200390087 · Cited by 8,559
Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200802248 · Cited by 5,702
Shape control of CdSe nanocrystals
Peng, X., Manna, L., Yang, W., Wickham, J., Scher, E., Kadavanich, A., & Alivisatos, A. P. (2000) · Nature · doi:10.1038/35003535 · Cited by 4,487
Control of Thickness and Orientation of Solution-Grown Silicon Nanowires
Holmes, J. D., Johnston, K. P., Doty, R. C., & Korgel, B. A. (2000) · Science · doi:10.1126/science.287.5457.1471 · Cited by 1,540
Shape Control of Semiconductor and Metal Oxide Nanocrystals through Nonhydrolytic Colloidal Routes
Jun, Y., Choi, J., & Cheon, J. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200503821 · Cited by 1,123
Metadata
- Authors
- Trentler, T. J., Hickman, K. M., Goel, S. C., Viano, A. M., Gibbons, P. C., & Buhro, W. E.
- Venue
- Science
- Published
- 1995-12-15
- Volume
- 270
- Issue
- 5243
- Pages
- 1791-1794
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2082087822
- Cited by
- 1,064
- References
- 0
- FWCI
- 5.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Solution-Liquid-Solid Growth of Crystalline III-V Semiconductors: An Analogy to Vapor-Liquid-Solid Growth. https://app.cochat.ai/papers/10.1126/science.270.5243.1791
- The paper
- Trentler, T. J., Hickman, K. M., Goel, S. C., Viano, A. M., Gibbons, P. C., & Buhro, W. E. (1995). Solution-Liquid-Solid Growth of Crystalline III-V Semiconductors: An Analogy to Vapor-Liquid-Solid Growth. Science. https://doi.org/10.1126/science.270.5243.1791
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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