The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Molecular Orientation and Two-Component Nature of the Crystalline Fraction of Spider Dragline Silk
Abstract
The molecular origin of the exceptional mechanical properties of spider silk is unclear. This paper presents solid-state 2 H nuclear magnetic resonance data from unoriented, oriented, and supercontracted fibers, indicating that the crystalline fraction of dragline silk consists of two types of alanine-rich regions, one that is highly oriented and one that is poorly oriented and less densely packed. A new model for the molecular-level structure of individual silk molecules and their arrangement in the fibers is proposed. These data suggest that it will be necessary to control the secondary structure of individual polymer molecules in order to obtain optimum properties in bio-inspired polymers.
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Cites
Quadrupolar echo deuteron magnetic resonance spectroscopy in ordered hydrocarbon chains
Davis, J. H., Jeffrey, K. R., Bloom, M., Valic, M. I., & Higgs, T. P. (1976) · Chemical Physics Letters · doi:10.1016/0009-2614(76)80392-2 · Cited by 1,330
An Adaptive Nonlinear Least-Squares Algorithm
Dennis, J. E., Gay, D. M., & Walsh, R. E. (1981) · ACM Transactions on Mathematical Software · doi:10.1145/355958.355965 · Cited by 930
Structure of a protein superfiber: spider dragline silk.
Xu, M., & Lewis, R. V. (1990) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.87.18.7120 · Cited by 671
The structure and properties of spider silk
Gosline, J. M., DeMont, M. E., & Denny, M. W. (1986) · Endeavour · doi:10.1016/0160-9327(86)90049-9 · Cited by 611
Algorithm 573: NL2SOL—An Adaptive Nonlinear Least-Squares Algorithm [E4]
Dennis, J. E., Gay, D. M., & Welsch, R. E. (1981) · ACM Transactions on Mathematical Software · doi:10.1145/355958.355966 · Cited by 405
Mechanical and thermal properties of dragline silk from the spider Nephila clavipes
Cunniff, P. M., Fossey, S. A., Auerbach, M. A., Song, J. W., Kaplan, D. L., Adams, W. W., Eby, R. K., Mahoney, D., & Vezie, D. L. (1994) · Polymers for Advanced Technologies · doi:10.1002/pat.1994.220050801 · Cited by 297
Comparative studies of fibroins
Warwicker, J. O. (1960) · Journal of Molecular Biology · doi:10.1016/s0022-2836(60)80046-0 · Cited by 272
Bloom, M., Davis, J. H., & Valič, M. I. (1980) · Canadian Journal of Physics · doi:10.1139/p80-196 · Cited by 230
Molecular mechanism of spider silk elasticity
Dong, Z., Lewis, R. V., & Middaugh, C. R. (1991) · Archives of Biochemistry and Biophysics · doi:10.1016/0003-9861(91)90262-h · Cited by 92
Cited by
Elastin: molecular description and function
Debelle, L., & Tamburro, A. M. (1999) · The International Journal of Biochemistry & Cell Biology · doi:10.1016/s1357-2725(98)00098-3 · Cited by 545
Decoding the secrets of spider silk
Eisoldt, L., Smith, A., & Scheibel, T. (2011) · Materials Today · doi:10.1016/s1369-7021(11)70057-8 · Cited by 342
Metadata
- Authors
- Simmons, A. H., Michal, C. A., & Jelinski, L. W.
- Venue
- Science
- Published
- 1996-01-05
- Volume
- 271
- Issue
- 5245
- Pages
- 84-87
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2037533379
- Cited by
- 632
- References
- 9
- FWCI
- 26.15
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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