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Soft-Landing of Polyatomic Ions at Fluorinated Self-Assembled Monolayer Surfaces
Abstract
A method of preparing modified surfaces, referred to as soft-landing, is described in which intact polyatomic ions are deposited from the gas phase into a monolayer fluorocarbon surface at room temperature. The ions are trapped in the fluorocarbon matrix for many hours. They are released, intact, upon sputtering at low or high energy or by thermal desorption, and their molecular compositions are confirmed by isotopic labeling and high-resolution mass measurements. The method is demonstrated for various silyl and pyridinium cations. Capture at the surface is favored when the ions bear bulky substituents that facilitate steric trapping in the matrix.
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Cited by
Studies of Low-Coordinate Iron Dinitrogen Complexes
Smith, J. M., Sadique, A. R., Cundari, T. R., Rodgers, K. R., Lukat-Rodgers, G., Lachicotte, R. J., Flaschenriem, C. J., Vela, J., & Holland, P. L. (2006) · Journal of the American Chemical Society · doi:10.1021/ja052707x · Cited by 323
Serine Octamers: Cluster Formation, Reactions, and Implications for Biomolecule Homochirality
Nanita, S. C., & Cooks, R. G. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200501328 · Cited by 184
Self-citationMass-Selective Soft-Landing of Protein Assemblies with Controlled Landing Energies
Mikhailov, V. A., Mize, T. H., Benesch, J. L. P., & Robinson, C. V. (2014) · Analytical Chemistry · doi:10.1021/ac5018327 · Cited by 71
Metadata
- Authors
- Miller, S. A., Luo, H., Pachuta, S. J., & Cooks, R. G.
- Venue
- Science
- Published
- 1997-03-07
- Volume
- 275
- Issue
- 5305
- Pages
- 1447-1450
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2066329637
- Cited by
- 216
- References
- 0
- FWCI
- 6.04
- Type
- journal article
- Language
- en
- Open access
- closed
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- Miller, S. A., Luo, H., Pachuta, S. J., & Cooks, R. G. (1997). Soft-Landing of Polyatomic Ions at Fluorinated Self-Assembled Monolayer Surfaces. Science. https://doi.org/10.1126/science.275.5305.1447
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.