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Soft-Landing of Polyatomic Ions at Fluorinated Self-Assembled Monolayer Surfaces

Miller, S. A., Luo, H., Pachuta, S. J., Cooks, R. G.·1997·Science

Abstract

A method of preparing modified surfaces, referred to as soft-landing, is described in which intact polyatomic ions are deposited from the gas phase into a monolayer fluorocarbon surface at room temperature. The ions are trapped in the fluorocarbon matrix for many hours. They are released, intact, upon sputtering at low or high energy or by thermal desorption, and their molecular compositions are confirmed by isotopic labeling and high-resolution mass measurements. The method is demonstrated for various silyl and pyridinium cations. Capture at the surface is favored when the ions bear bulky substituents that facilitate steric trapping in the matrix.

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Metadata

Authors
Miller, S. A., Luo, H., Pachuta, S. J., & Cooks, R. G.
Venue
Science
Published
1997-03-07
Volume
275
Issue
5305
Pages
1447-1450
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2066329637
Cited by
216
References
0
FWCI
6.04
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Soft-Landing of Polyatomic Ions at Fluorinated Self-Assembled Monolayer Surfaces. https://app.cochat.ai/papers/10.1126/science.275.5305.1447
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Miller, S. A., Luo, H., Pachuta, S. J., & Cooks, R. G. (1997). Soft-Landing of Polyatomic Ions at Fluorinated Self-Assembled Monolayer Surfaces. Science. https://doi.org/10.1126/science.275.5305.1447

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.