The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.
Direct Measurement of Angles Between Bond Vectors in High-Resolution NMR
Abstract
Angles between two interatomic vectors are measured for structure elucidation in solution nuclear magnetic resonance (NMR). The angles can be determined directly by using the effects of dipole-dipole cross-correlated relaxation of double-quantum and zero-quantum coherences. The measured rates can be directly related to the angular geometry without need for calibration of a Karplus-type curve, as is the case for scalar coupling measurements, and depend only on the rotational correlation time of the molecule as an empirical parameter. This makes the determination of torsional angles independent from the measurement of coupling constants. The two interatomic vectors can in principle be arbitrarily far apart. The method was demonstrated on the measurement of the peptide backbone angle ψ in the protein rhodniin, which is difficult to determine in solution by NMR spectroscopy.
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Citations
Cites
The Principles of Nuclear Magnetism
Abragam, A., & Hebel, L. C. (1961) · American Journal of Physics · doi:10.1119/1.1937646 · Cited by 15,792
NMR with Proteins and Nucleic Acids
Wüthrich, K. (1986) · Europhysics News · doi:10.1051/epn/19861701011 · Cited by 7,989
Relaxation Effects in Nuclear Magnetic Resonance Absorption
Bloembergen, N., Purcell, E. M., & Pound, R. V. (1948) · Physical Review · doi:10.1103/physrev.73.679 · Cited by 6,528
Lipari, G., & Szabo, A. (1982) · Journal of the American Chemical Society · doi:10.1021/ja00381a009 · Cited by 3,777
Relaxation Processes in a System of Two Spins
Solomon, I. (1955) · Physical Review · doi:10.1103/physrev.99.559 · Cited by 3,278
Contact Electron-Spin Coupling of Nuclear Magnetic Moments
Karplus, M. (1959) · The Journal of Chemical Physics · doi:10.1063/1.1729860 · Cited by 2,969
Model-free approach to the interpretation of nuclear magnetic resonance relaxation in macromolecules
Lipari, G. (1982) · Journal of the American Chemical Society · Cited by 2,525
Vicinal Proton Coupling in Nuclear Magnetic Resonance
Karplus, M. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00901a059 · Cited by 2,444
Kay, L. E., Torchia, D. A., & Bax, A. (1989) · Biochemistry · doi:10.1021/bi00449a003 · Cited by 1,768
Ikura, M., Kay, L. E., & Bax, A. (1990) · Biochemistry · doi:10.1021/bi00471a022 · Cited by 918
Metadata
- Authors
- Reif, B., Hennig, M., & Griesinger, C.
- Venue
- Science
- Published
- 1997-05-23
- Volume
- 276
- Issue
- 5316
- Pages
- 1230-1233
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1991917686
- Cited by
- 310
- References
- 26
- FWCI
- 18.34
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
