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Conductance of a Molecular Junction
Abstract
Molecules of benzene-1,4-dithiol were self-assembled onto the two facing gold electrodes of a mechanically controllable break junction to form a statically stable gold-sulfur-aryl-sulfur-gold system, allowing for direct observation of charge transport through the molecules. Current-voltage measurements at room temperature demonstrated a highly reproducible apparent gap at about 0.7 volt, and the conductance-voltage curve showed two steps in both bias directions. This study provides a quantative measure of the conductance of a junction containing a single molecule, which is a fundamental step in the emerging area of molecular-scale electronics.
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Citations
Cited by
Negishi, Y., Nobusada, K., & Tsukuda, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja042218h · Cited by 1,646
Molecular Electronic Junctions
McCreery, R. L. (2004) · Chemistry of Materials · doi:10.1021/cm049517q · Cited by 555
Unimolecular Electrical Rectifiers
Metzger, R. M. (2003) · Chemical Reviews · doi:10.1021/cr020413d · Cited by 518
Naber, W. J. M., Faez, S., & Wiel, W. G. V. D. (2007) · Journal of Physics D: Applied Physics · doi:10.1088/0022-3727/40/12/r01 · Cited by 459
Molecular junctions based on aromatic coupling
Wu, S., González, M. T., Huber, R., Grunder, S., Mayor, M., Schönenberger, C., & Calame, M. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2008.237 · Cited by 389
Metadata
- Authors
- Reed, M. A., Zhou, C., Muller, C. J., Burgin, T. P., & Tour, J. M.
- Venue
- Science
- Published
- 1997-10-10
- Volume
- 278
- Issue
- 5336
- Pages
- 252-254
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2045725637
- Cited by
- 3,458
- References
- 0
- FWCI
- 67.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Reed, M. A., Zhou, C., Muller, C. J., Burgin, T. P., & Tour, J. M. (1997). Conductance of a Molecular Junction. Science. https://doi.org/10.1126/science.278.5336.252
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.