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Large-Cage Zeolite Structures with Multidimensional 12-Ring Channels
Abstract
Zeolite type structures with large cages interconnected by multidimensional 12-ring (rings of 12 tetrahedrally coordinated atoms) channels have been synthesized; more than a dozen large-pore materials were created in three different topologies with aluminum (or gallium), cobalt (or manganese, magnesium, or zinc), and phosphorus at the tetrahedral coordination sites. Tetragonal UCSB-8 has an unusually large cage built from 64 tetrahedral atoms and connected by an orthogonal channel system with 12-ring apertures in two dimensions and 8-ring apertures in the third. Rhombohedral UCSB-10 and hexagonal UCSB-6 are structurally related to faujasite and its hexagonal polymorph, respectively, and have large cages connected by 12-ring channels in all three dimensions.
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Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
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Zheng, N., Bu, X., Wang, B., & Feng, P. (2002) · Science · doi:10.1126/science.1078663 · Cited by 494
Self-citationSOMC@PMS. Surface Organometallic Chemistry at Periodic Mesoporous Silica
Anwander, R. (2001) · Chemistry of Materials · doi:10.1021/cm0111534 · Cited by 320
Metadata
- Authors
- Bu, X., Feng, P., & Stucky, G. D.
- Venue
- Science
- Published
- 1997-12-19
- Volume
- 278
- Issue
- 5346
- Pages
- 2080-2085
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2055923802
- Cited by
- 329
- References
- 1
- FWCI
- 16.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bu, X., Feng, P., & Stucky, G. D. (1997). Large-Cage Zeolite Structures with Multidimensional 12-Ring Channels. Science. https://doi.org/10.1126/science.278.5346.2080
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