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Chiral Spaces: Dissymmetric Capsules Through Self-Assembly
Open accessAbstract
Molecules with self-complementary surfaces interact through weak intermolecular forces to form assemblies, and the assembled states frequently exhibit distinctive properties. Described here are systems in which symmetrical molecules assemble through hydrogen bonding to produce capsules with dissymmetric cavities. The capsules form and dissipate on a time scale that permits their direct observation by nuclear magnetic resonance measurements, and they act as hosts for smaller molecular guests. Molecular recognition of chiral guests, such as naturally occurring terpenes, determines which dissymmetric cavities are preferentially formed in the assembly process.
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Citations
Cited by
Supramolecular Chirality in Self-Assembled Systems
Liu, M., Zhang, L., & Wang, T. (2015) · Chemical Reviews · doi:10.1021/cr500671p · Cited by 2,250
Extended surface chirality from supramolecular assemblies of adsorbed chiral molecules
Ortega Lorenzo, M., Baddeley, C. J., Muryn, C., & Raval, R. (2000) · Nature · doi:10.1038/35006031 · Cited by 549
Reinhoudt, D. N., & Crego-Calama, M. (2002) · Science · doi:10.1126/science.1069197 · Cited by 493
Complete asymmetric induction of supramolecular chirality in a hydrogen-bonded assembly
Prins, L. J., Huskens, J., de Jong, F., Timmerman, P., & Reinhoudt, D. N. (1999) · Nature · doi:10.1038/19053 · Cited by 481
Supramolecular chirality of self-assembled systems in solution
Mateos-Timoneda, M. A., Crego-Calama, M., & Reinhoudt, D. N. (2004) · Chemical Society Reviews · doi:10.1039/b305550g · Cited by 444
Metadata
- Authors
- Rivera, J. M., Martı́n, T., & Rebek, J.
- Venue
- Science
- Published
- 1998-02-13
- Volume
- 279
- Issue
- 5353
- Pages
- 1021-1023
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1994014392
- Cited by
- 199
- References
- 0
- FWCI
- 12.74
- Type
- journal article
- Language
- en
- Open access
- green
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