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Gas-Phase Ionic Reactions: Dynamics and Mechanism of Nucleophilic Displacements
Abstract
Nucleophilic displacement reactions (the S N 2 reaction) of ions in the gas phase are a prototypical reaction system that allows a study of dynamics, mechanisms, and structure-energy relations. This article reviews aspects of the kinetics (especially the applicability of statistical reaction rate theory), the relation of structure and reactivity, and the effects of small numbers of solvent molecules on the reaction and compares the behavior of the ionic reaction in the gas phase with that in solution.
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Cited by
Organic Reactions in Microdroplets: Reaction Acceleration Revealed by Mass Spectrometry
Yan, X., Bain, R. M., & Cooks, R. G. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201602270 · Cited by 583
Mass Spectrometric Studies of Organic Ion/Molecule Reactions
Gronert, S. (2001) · Chemical Reviews · doi:10.1021/cr9900836 · Cited by 268
Metadata
- Authors
- Chabinyc, M. L., Craig, S. L., Regan, C. K., & Brauman, J. I.
- Venue
- Science
- Published
- 1998-03-20
- Volume
- 279
- Issue
- 5358
- Pages
- 1882-1886
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2051833948
- Cited by
- 294
- References
- 0
- FWCI
- 13.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Gas-Phase Ionic Reactions: Dynamics and Mechanism of Nucleophilic Displacements. https://app.cochat.ai/papers/10.1126/science.279.5358.1882
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- Chabinyc, M. L., Craig, S. L., Regan, C. K., & Brauman, J. I. (1998). Gas-Phase Ionic Reactions: Dynamics and Mechanism of Nucleophilic Displacements. Science. https://doi.org/10.1126/science.279.5358.1882
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
