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A "Green" Route to Adipic Acid: Direct Oxidation of Cyclohexenes with 30 Percent Hydrogen Peroxide
Abstract
Currently, the industrial production of adipic acid uses nitric acid oxidation of cyclohexanol or a cyclohexanol/cyclohexanone mixture. The nitrous oxide emission from this process measurably contributes to global warming and ozone depletion. Therefore, the development of an adipic acid production process that is less damaging to the environment is an important subject in chemical research. Cyclohexene can now be oxidized directly to colorless crystalline adipic acid with aqueous 30 percent hydrogen peroxide under organic solvent- and halide-free conditions, which could provide an ideal solution to this serious problem.
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Cited by
The Hitchhiker’s Guide to Flow Chemistry
Plutschack, M. B., Pieber, B., Gilmore, K., & Seeberger, P. H. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00183 · Cited by 1,995
Green oxidation with aqueous hydrogen peroxide
Noyori, R., Aoki, M., & Sato, K. (2003) · Chemical Communications · doi:10.1039/b303160h · Cited by 1,085
Self-citationRecent advances in oxidative valorization of lignin
Ma, R., Guo, M., & Zhang, X. (2018) · Catalysis Today · doi:10.1016/j.cattod.2017.05.101 · Cited by 219
Guo, X., Xu, M., She, M., Zhu, Y., Shi, T., Chen, Z., Peng, L., Guo, X., Lin, M., & Ding, W. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201911749 · Cited by 46
Ansaloni, S., Russo, N., & Pirone, R. (2018) · Waste and Biomass Valorization · doi:10.1007/s12649-017-9947-4 · Cited by 26
Metadata
- Authors
- Sato, K., Aoki, M., & Noyori, R.
- Venue
- Science
- Published
- 1998-09-11
- Volume
- 281
- Issue
- 5383
- Pages
- 1646-1647
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2017215902
- Cited by
- 841
- References
- 0
- FWCI
- 10.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: A "Green" Route to Adipic Acid: Direct Oxidation of Cyclohexenes with 30 Percent Hydrogen Peroxide. https://app.cochat.ai/papers/10.1126/science.281.5383.1646
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- Sato, K., Aoki, M., & Noyori, R. (1998). A "Green" Route to Adipic Acid: Direct Oxidation of Cyclohexenes with 30 Percent Hydrogen Peroxide. Science. https://doi.org/10.1126/science.281.5383.1646
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
