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Solution Properties of Single-Walled Carbon Nanotubes
Abstract
Naked metallic and semiconducting single-walled carbon nanotubes (SWNTs) were dissolved in organic solutions by derivatization with thionychloride and octadecylamine. Both ionic (charge transfer) and covalent solution-phase chemistry with concomitant modulation of the SWNT band structure were demonstrated. Solution-phase near-infrared spectroscopy was used to study the effects of chemical modifications on the band gaps of the SWNTs. Reaction of soluble SWNTs with dichlorocarbene led to functionalization of the nanotube walls.
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Citations
Cited by
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Ma, P.-C., Siddiqui, N. A., Marom, G., & Kim, J.-K. (2010) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2010.07.003 · Cited by 3,414
Graphene/Polymer Nanocomposites
Kim, H., Abdala, A. A., & Macosko, C. W. (2010) · Macromolecules · doi:10.1021/ma100572e · Cited by 3,406
Chemical oxidation of multiwalled carbon nanotubes
Datsyuk, V., Kalyva, M., Papagelis, K., Parthenios, J., Tasis, D., Siokou, A., Kallitsis, I., & Galiotis, C. (2008) · Carbon · doi:10.1016/j.carbon.2008.02.012 · Cited by 2,747
Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization
Chen, R. J., Zhang, Y., Wang, D., & Dai, H. (2001) · Journal of the American Chemical Society · doi:10.1021/ja010172b · Cited by 2,534
Georgakilas, V., Perman, J. A., Tucek, J., & Zboril, R. (2015) · Chemical Reviews · doi:10.1021/cr500304f · Cited by 2,147
Metadata
- Authors
- Chen, J., Hamon, M. A., Hu, H., Chen, Y., Rao, A. M., Eklund, P. C., & Haddon, R. C.
- Venue
- Science
- Published
- 1998-10-02
- Volume
- 282
- Issue
- 5386
- Pages
- 95-98
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2046741906
- Cited by
- 2,536
- References
- 0
- FWCI
- 29.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, J., Hamon, M. A., Hu, H., Chen, Y., Rao, A. M., Eklund, P. C., & Haddon, R. C. (1998). Solution Properties of Single-Walled Carbon Nanotubes. Science. https://doi.org/10.1126/science.282.5386.95
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