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Solution Properties of Single-Walled Carbon Nanotubes

Chen, Jian, Hamon, Mark A., Hu, Hui, Chen, Yongsheng, Rao, Apparao M., Eklund, Peter C., Haddon, Robert C.·1998·Science

Abstract

Naked metallic and semiconducting single-walled carbon nanotubes (SWNTs) were dissolved in organic solutions by derivatization with thionychloride and octadecylamine. Both ionic (charge transfer) and covalent solution-phase chemistry with concomitant modulation of the SWNT band structure were demonstrated. Solution-phase near-infrared spectroscopy was used to study the effects of chemical modifications on the band gaps of the SWNTs. Reaction of soluble SWNTs with dichlorocarbene led to functionalization of the nanotube walls.

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Metadata

Authors
Chen, J., Hamon, M. A., Hu, H., Chen, Y., Rao, A. M., Eklund, P. C., & Haddon, R. C.
Venue
Science
Published
1998-10-02
Volume
282
Issue
5386
Pages
95-98
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2046741906
Cited by
2,536
References
0
FWCI
29.07
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Solution Properties of Single-Walled Carbon Nanotubes. https://app.cochat.ai/papers/10.1126/science.282.5386.95
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Chen, J., Hamon, M. A., Hu, H., Chen, Y., Rao, A. M., Eklund, P. C., & Haddon, R. C. (1998). Solution Properties of Single-Walled Carbon Nanotubes. Science. https://doi.org/10.1126/science.282.5386.95

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.