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Ordered Mesoporous Polymers of Tunable Pore Size from Colloidal Silica Templates
Abstract
Ordered mesoporous polymers have been prepared by replication of colloidal crystals made from silica spheres 35 nanometers in diameter. The pores in the colloidal crystals were filled with divinylbenzene (DVB), ethyleneglycol dimethacrylate (EDMA), or a mixture of the two. Polymerization and subsequent dissolution of the silica template leaves a polycrystalline network of interconnected pores. When mixtures of DVB and EDMA are used, the pore size of the polymer replicas can be varied continuously between 35 and 15 nanometers because the polymer shrinks when the silica template is removed.
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Cited by
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
Chen, C., Kang, Y., Huo, Z., Zhu, Z., Huang, W., Xin, H. L., Snyder, J. D., Li, D., Herron, J. A., Mavrikakis, M., et al. (2014) · Science · doi:10.1126/science.1249061 · Cited by 2,765
Yin, Y., Lu, Y., Gates, B., & Xia, Y. (2001) · Journal of the American Chemical Society · doi:10.1021/ja011048v · Cited by 915
Nanoporous Polymers for Hydrogen Storage
Germain, J., Fréchet, J. M. J., & Svec, F. (2009) · Small · doi:10.1002/smll.200801762 · Cited by 432
Template-Directed Preparation of Macroporous Polymers with Oriented and Crystalline Arrays of Voids
Jiang, P., Hwang, K. S., Mittleman, D. M., Bertone, J. F., & Colvin, V. L. (1999) · Journal of the American Chemical Society · doi:10.1021/ja9903476 · Cited by 373
Dong, H., Paramonov, S. E., Aulisa, L., Bakota, E. L., & Hartgerink, J. D. (2007) · Journal of the American Chemical Society · doi:10.1021/ja072536r · Cited by 344
Metadata
- Authors
- Johnson, S. A., Ollivier, P. J., & Mallouk, T. E.
- Venue
- Science
- Published
- 1999-02-12
- Volume
- 283
- Issue
- 5404
- Pages
- 963-965
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2005852883
- Cited by
- 603
- References
- 0
- FWCI
- 24.30
- Type
- journal article
- Language
- en
- Open access
- closed
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- Johnson, S. A., Ollivier, P. J., & Mallouk, T. E. (1999). Ordered Mesoporous Polymers of Tunable Pore Size from Colloidal Silica Templates. Science. https://doi.org/10.1126/science.283.5404.963
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
