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High H 2 Uptake by Alkali-Doped Carbon Nanotubes Under Ambient Pressure and Moderate Temperatures
Abstract
Lithium- or potassium-doped carbon nanotubes can absorb ∼20 or ∼14 weight percent of hydrogen at moderate (200° to 400°C) or room temperatures, respectively, under ambient pressure. These values are greater than those of metal hydride and cryoadsorption systems. The hydrogen stored in the lithium- or potassium-doped carbon nanotubes can be released at higher temperatures, and the sorption-desorption cycle can be repeated with little decrease in the sorption capacity. The high hydrogen-uptake capacity of these systems may be derived from the special open-edged, layered structure of the carbon nanotubes made from methane, as well as the catalytic effect of alkali metals.
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Cites
Spectrometric Identification of Organic Compounds
Silverstein, R. M., & Bassler, G. C. (1962) · Journal of Chemical Education · doi:10.1021/ed039p546 · Cited by 14,272
Cited by
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Schlapbach, L., & Züttel, A. (2001) · Nature · doi:10.1038/35104634 · Cited by 8,865
(2018) · doi:10.1016/j.enconman.2018.03.088 · Cited by 1,832
Gas molecule adsorption in carbon nanotubes and nanotube bundles
Zhao, J., Buldum, A., Han, J., & Lu, J. P. (2002) · Nanotechnology · doi:10.1088/0957-4484/13/2/312 · Cited by 1,163
Progress and problems in hydrogen storage methods
Zhou, L. (2005) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2004.05.005 · Cited by 691
Hydrogen storage: beyond conventional methods
Dalebrook, A. F., Gan, W., Grasemann, M., Moret, S., & Laurenczy, G. (2013) · Chemical Communications · doi:10.1039/c3cc43836h · Cited by 503
Metadata
- Authors
- Chen, P., Wu, X., Lin, J., & Tan, K. L.
- Venue
- Science
- Published
- 1999-07-02
- Volume
- 285
- Issue
- 5424
- Pages
- 91-93
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2011448647
- Cited by
- 1,164
- References
- 1
- FWCI
- 50.89
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, P., Wu, X., Lin, J., & Tan, K. L. (1999). High H 2 Uptake by Alkali-Doped Carbon Nanotubes Under Ambient Pressure and Moderate Temperatures. Science. https://doi.org/10.1126/science.285.5424.91
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.