The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms
Abstract
More than half of the 170 million metric tons of polymers produced each year are polyolefins. Current technology uses highly active cationic catalysts, which suffer from an inability to tolerate heteroatoms such as oxygen, nitrogen, and sulfur. These systems require scrupulously clean starting materials and activating cocatalysts. A family of catalysts has been developed whose members are tolerant of both heteroatoms and less pure starting materials. These heteroatom-tolerant neutral late transition metal complexes are in fact highly active systems that produce high-molecular-weight polyethylene, polymerize functionalized olefins, and require no cocatalyst.
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Citations
Cites
Nickel catalysis for ethylene homo- and co-polymerization
Klabunde, U., & Itten, S. D. (1987) · Journal of Molecular Catalysis · doi:10.1016/0304-5102(87)80023-8 · Cited by 332
Cited by
Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts
Chen, Z., & Brookhart, M. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00225 · Cited by 405
Catalytic Hydroxylation of Polyethylenes
Bunescu, A., Lee, S., Li, Q., & Hartwig, J. F. (2017) · ACS Central Science · doi:10.1021/acscentsci.7b00255 · Cited by 252
Metadata
- Authors
- Younkin, T. R., Connor, E. F., Henderson, J. I., Friedrich, S. K., Grubbs, R. H., & Bansleben, D. A.
- Venue
- Science
- Published
- 2000-01-21
- Volume
- 287
- Issue
- 5452
- Pages
- 460-462
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2012591289
- Cited by
- 1,130
- References
- 1
- FWCI
- 51.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Younkin, T. R., Connor, E. F., Henderson, J. I., Friedrich, S. K., Grubbs, R. H., & Bansleben, D. A. (2000). Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms. Science. https://doi.org/10.1126/science.287.5452.460
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
