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Real-Time Observation of Adsorbate Atom Motion Above a Metal Surface

Petek, Hrvoje, Weida, Miles J., Nagano, Hisashi, Ogawa, Susumu·2000·Science

Abstract

The dynamics of cesium atom motion above the copper(111) surface following electronic excitation with light was studied with femtosecond (10 –15 seconds) time resolution. Unusual changes in the surface electronic structure within 160 femtoseconds after excitation, observed by time-resolved two-photon photoemission spectroscopy, are attributed to atomic motion in a copper–cesium bond-breaking process. Describing the change in energy of the cesium antibonding state with a simple classical model provides information on the mechanical forces acting on cesium atoms that are “turned on” by photoexcitation. Within 160 femtoseconds, the copper–cesium bond extends by 0.35 angstrom from its equilibrium value.

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Metadata

Authors
Petek, H., Weida, M. J., Nagano, H., & Ogawa, S.
Venue
Science
Published
2000-05-26
Volume
288
Issue
5470
Pages
1402-1404
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W1999172376
Cited by
268
References
0
FWCI
10.19
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Real-Time Observation of Adsorbate Atom Motion Above a Metal Surface. https://app.cochat.ai/papers/10.1126/science.288.5470.1402
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Petek, H., Weida, M. J., Nagano, H., & Ogawa, S. (2000). Real-Time Observation of Adsorbate Atom Motion Above a Metal Surface. Science. https://doi.org/10.1126/science.288.5470.1402

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.