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Creating Long-Lived Superhydrophobic Polymer Surfaces Through Mechanically Assembled Monolayers
Abstract
We show that elastomeric surfaces can be tailored using “mechanically assembled monolayers” (MAMs), structures that are fabricated by combining self-assembly of surface grafting molecules with mechanical manipulation of the grafting points in the underlying elastic surface. The versatility of this surface modification method is demonstrated by fabricating MAMs with semifluorinated (SF) molecules. These SF-MAMs have superior nonwetting and barrier properties in that they are “superhydrophobic” and nonpermeable. We also establish that these material characteristics do not deteriorate even after prolonged exposure to water, which usually causes surface reconstruction in conventionally prepared SF self-assembled monolayers.
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Cited by
Bioinspired Surfaces with Superwettability: New Insight on Theory, Design, and Applications
Wang, S., Liu, K., Yao, X., & Jiang, L. (2015) · Chemical Reviews · doi:10.1021/cr400083y · Cited by 1,646
Efimenko, K., Wallace, W. E., & Genzer, J. (2002) · Journal of Colloid and Interface Science · doi:10.1006/jcis.2002.8594 · Cited by 757
Self-citationSuperhydrophobic conjugated microporous polymers for separation and adsorption
Li, A., Sun, H.-X., Tan, D.-Z., Fan, W.-J., Wen, S.-H., Qing, X.-J., Li, G.-X., Li, S.-Y., & Deng, W.-Q. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01092a · Cited by 601
Interfacial Water at Hydrophobic and Hydrophilic Surfaces: Slip, Viscosity, and Diffusion
Sendner, C., Horinek, D., Bocquet, L., & Netz, R. R. (2009) · Langmuir · doi:10.1021/la901314b · Cited by 567
Russell, T. P. (2002) · Science · doi:10.1126/science.1075997 · Cited by 494
Metadata
- Authors
- Genzer, J., & Efimenko, K.
- Venue
- Science
- Published
- 2000-12-15
- Volume
- 290
- Issue
- 5499
- Pages
- 2130-2133
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1978147067
- Cited by
- 585
- References
- 0
- FWCI
- 6.45
- Type
- journal article
- Language
- en
- Open access
- closed
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