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Cited by 761

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

An Efficient Two-Photon-Generated Photoacid Applied to Positive-Tone 3D Microfabrication

Zhou, Wenhui, Kuebler, Stephen M., Braun, Kevin L., Yu, Tianyue, Cammack, J. Kevin, Ober, Christopher K., Perry, Joseph W., Marder, Seth R.·2002·Science

Abstract

A two-photon–activatable photoacid generator, based on a bis [(diarylamino) styryl]benzene core with covalently attached sulfonium moieties, has been synthesized. The photoacid generator has both a large two-photon absorption cross section (δ = 690 × 10 −50 centimeter 4 second per photon) and a high quantum yield for the photochemical generation of acid (φ H + = 0.5). Under near-infrared laser irradiation, the molecule produces acid after two-photon excitation and initiates the polymerization of epoxides at an incident intensity that is one to two orders of magnitude lower than that needed for conventional ultraviolet-sensitive initiators. This photoacid generator was used in conjunction with a positive-tone chemically amplified resist for the fabrication of a three-dimensional (3D) microchannel structure.

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Metadata

Authors
Zhou, W., Kuebler, S. M., Braun, K. L., Yu, T., Cammack, J. K., Ober, C. K., Perry, J. W., & Marder, S. R.
Venue
Science
Published
2002-05-10
Volume
296
Issue
5570
Pages
1106-1109
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2139993630
Cited by
761
References
2
FWCI
39.38
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: An Efficient Two-Photon-Generated Photoacid Applied to Positive-Tone 3D Microfabrication. https://app.cochat.ai/papers/10.1126/science.296.5570.1106
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Zhou, W., Kuebler, S. M., Braun, K. L., Yu, T., Cammack, J. K., Ober, C. K., Perry, J. W., & Marder, S. R. (2002). An Efficient Two-Photon-Generated Photoacid Applied to Positive-Tone 3D Microfabrication. Science. https://doi.org/10.1126/science.296.5570.1106

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