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Native functionality in triple catalytic cross-coupling: sp 3 C–H bonds as latent nucleophiles
Open accessAbstract
A tip of the HAT to C-C bond formation: Iridium and nickel are already a proven team for forging carbon-carbon bonds. The iridium harvests blue light from a simple light-emitting diode and orchestrates the coupling by the nickel. Shaw et al. now add a third player to the team, a hydrogen atom transfer (HAT) catalyst (see the Perspective by Fruit). Together, the trio of catalysts can link bromo- or chloroaryl rings directly to C-H sites adjacent to nitrogen or oxygen, with no need for prior modification. The reaction is highly selective across a broad range of substrates. Science , this issue p. 1304 ; see also p. 1277
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
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Metadata
- Authors
- Shaw, M. H., Shurtleff, V. W., Terrett, J. A., Cuthbertson, J. D., & MacMillan, D. W. C.
- Venue
- Science
- Published
- 2016-06-10
- Volume
- 352
- Issue
- 6291
- Pages
- 1304-1308
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2343326307
- Cited by
- 643
- References
- 1
- FWCI
- 32.67
- Type
- journal article
- Language
- en
- Open access
- green
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