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Defibrillation of soft porous metal-organic frameworks with electric fields

Knebel, A., Geppert, B., Volgmann, K., Kolokolov, D. I., Stepanov, A. G., Twiefel, J., Heitjans, P., Volkmer, D., Caro, J.·2017·Science

Abstract

Tuning porosity with electric fields: Many metal-organic framework (MOF) compounds exhibit soft porosity—i.e., their lattices can undergo considerable deformation. Knebel et al. formed membrane layers of the MOF ZIF-8 and found that it was converted into a polar polymorph with a stiffer lattice in response to an applied electric field (see the Perspective by Gascon). This change reduced gas transport but, for certain gas mixtures such as propane and propene, also improved their separation factor. Science , this issue p. 347 ; see also p. 303

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Crossref · 10.1126/science.aal2456

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Metadata

Authors
Knebel, A., Geppert, B., Volgmann, K., Kolokolov, D. I., Stepanov, A. G., Twiefel, J., Heitjans, P., Volkmer, D., & Caro, J.
Venue
Science
Published
2017-10-20
Volume
358
Issue
6361
Pages
347-351
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2765446679
Cited by
461
References
2
FWCI
16.64
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Defibrillation of soft porous metal-organic frameworks with electric fields. https://app.cochat.ai/papers/10.1126/science.aal2456
The paper
Knebel, A., Geppert, B., Volgmann, K., Kolokolov, D. I., Stepanov, A. G., Twiefel, J., Heitjans, P., Volkmer, D., & Caro, J. (2017). Defibrillation of soft porous metal-organic frameworks with electric fields. Science. https://doi.org/10.1126/science.aal2456

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.