The DOI matches its Crossref record; 20 of the 20 references it cites were found in a registry or an index.
Arylsulfonylacetamides as bifunctional reagents for alkene aminoarylation
Open accessAbstract
Arenes and amides from a single source: Pharmaceutical synthesis often requires the formation of adjacent carbon-carbon and carbon-nitrogen bonds. Monos et al. present a method that delivers the carbon and nitrogen components in a single reagent, specifically, an aryl ring tethered through sulfur dioxide to an amide. A light-activated catalyst primes an olefin to react with the nitrogen, which in turn leads to migration of the aryl ring and loss of the sulfur bridge. The efficient room-temperature process is applicable to a variety of different arenes, including heterocycles. Science , this issue p. 1369
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Recent progress in the generation and use of nitrogen-centred radicals
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Radical aryl migration reactions and synthetic applications
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Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines
Musacchio, A. J., Lainhart, B. C., Zhang, X., Naguib, S. G., Sherwood, T. C., & Knowles, R. R. (2017) · Science · doi:10.1126/science.aal3010 · Cited by 400
Cited by
Visible-Light-Driven Reductive Carboarylation of Styrenes with CO 2 and Aryl Halides
Wang, H., Gao, Y., Zhou, C., & Li, G. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c03144 · Cited by 303
Desulfonylation via Radical Process: Recent Developments in Organic Synthesis
Chu, X.-Q., Ge, D., Cui, Y.-Y., Shen, Z.-L., & Li, C.-J. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00084 · Cited by 259
Metadata
- Authors
- Monos, T. M., McAtee, R. C., & Stephenson, C. R. J.
- Venue
- Science
- Published
- 2018-09-28
- Volume
- 361
- Issue
- 6409
- Pages
- 1369-1373
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2893361790
- Cited by
- 355
- References
- 20
- FWCI
- 10.75
- Type
- journal article
- Language
- en
- Open access
- green
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