The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
A linear cobalt(II) complex with maximal orbital angular momentum from a non-Aufbau ground state
Abstract
Cobalt unfettered by its ligand field: Applied magnetic fields induce a field in any compound with unpaired electrons. However, for the induced field to persist once the applied field is gone, the electrons must be configured to manifest orbital angular momentum. Generally, the influence of ligands severely restricts that property in transition metal complexes. Bunting et al. now show that a cobalt ion is just barely affected by two linearly coordinated carbon ligands and, as such, exhibits maximal orbital angular momentum. Although its magnetic properties mainly pertain at very low temperature, its structure offers a more general design principle. Science , this issue p. eaat7319
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Encyclopedia of Inorganic and Bioinorganic Chemistry
(2011) · Wiley eBooks · doi:10.1002/9781119951438 · Cited by 1,585
Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time
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Metadata
- Authors
- Bunting, P. C., Atanasov, M., Damgaard-Møller, E., Perfetti, M., Crassee, I., Orlita, M., Overgaard, J., van Slageren, J., Neese, F., & Long, J. R.
- Venue
- Science
- Published
- 2018-12-21
- Volume
- 362
- Issue
- 6421
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2901080522
- Cited by
- 388
- References
- 36
- FWCI
- 11.63
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bunting, P. C., Atanasov, M., Damgaard-Møller, E., Perfetti, M., Crassee, I., Orlita, M., Overgaard, J., van Slageren, J., Neese, F., & Long, J. R. (2018). A linear cobalt(II) complex with maximal orbital angular momentum from a non-Aufbau ground state. Science. https://doi.org/10.1126/science.aat7319
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