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Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes
Open accessAbstract
Two-for-one approach to photoredox: In photoredox catalysis, an excited chromophore typically activates a single reactant either by oxidizing or reducing it. Ghosh et al. used a semiconductor catalyst to activate two reactants at once by quenching both an excited electron and the residual positive hole (see the Perspective by Swift). As such, two different reactive carbon or halide fragments could be appended to separate sites on an aryl ring. The catalyst also tolerated strong nucleophiles such as cyanide and could be recovered easily and reused. Science , this issue p. 360 ; see also p. 320
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Cited by
Xiao, X., Gao, Y., Zhang, L., Zhang, J., Zhang, Q., Li, Q., Bao, H., Zhou, J., Miao, S., Chen, N., et al. (2020) · Advanced Materials · doi:10.1002/adma.202003082 · Cited by 528
Floatable photocatalytic hydrogel nanocomposites for large-scale solar hydrogen production
Lee, W. H., Lee, C. W., Cha, G. D., Lee, B.-H., Jeong, J. H., Park, H., Heo, J., Bootharaju, M. S., Sunwoo, S.-H., Kim, J. H., et al. (2023) · Nature Nanotechnology · doi:10.1038/s41565-023-01385-4 · Cited by 394
Yan, Y., Li, C., Wu, Y., Gao, J., & Zhang, Q. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta03749d · Cited by 260
Zhu, C., Yue, H., Jia, J., & Rueping, M. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202013852 · Cited by 259
(2021) · doi:10.1038/s41467-021-26817-4 · Cited by 222
Metadata
- Authors
- Ghosh, I., Khamrai, J., Savateev, A., Shlapakov, N., Antonietti, M., & König, B.
- Venue
- Science
- Published
- 2019-07-26
- Volume
- 365
- Issue
- 6451
- Pages
- 360-366
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2963566360
- Cited by
- 591
- References
- 1
- FWCI
- 29.31
- Type
- journal article
- Language
- en
- Open access
- green
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- Ghosh, I., Khamrai, J., Savateev, A., Shlapakov, N., Antonietti, M., & König, B. (2019). Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes. Science. https://doi.org/10.1126/science.aaw3254
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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