The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Aminoalkyl radicals as halogen-atom transfer agents for activation of alkyl and aryl halides
Open accessAbstract
Amines as a gateway to alkyl radicals: In recent years, photoredox catalysis driven by blue light has often been used to oxidize carbon centers adjacent to nitrogen. Constantin et al. now show that these aminoalkyl radicals can, in turn, conveniently strip iodine atoms from a variety of alkyl carbons. The new alkyl radicals that result readily undergo deuteration and couplings such as alkylation, allylation, and olefination. The upshot is that simple amines can replace more hazardous conventional reagents such as trialkyltin compounds in the homolytic activation and functionalization of halocarbons. Science , this issue p. 1021
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A new mixing of Hartree–Fock and local density-functional theories
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Cited by
Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis
Chan, A. Y., Perry, I. B., Bissonnette, N. B., Buksh, B. F., Edwards, G. A., Frye, L. I., Garry, O. L., Lavagnino, M. N., Li, B. X., Liang, Y., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00383 · Cited by 1,754
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
New Redox Strategies in Organic Synthesis by Means of Electrochemistry and Photochemistry
Liu, J., Lu, L., Wood, D., & Lin, S. (2020) · ACS Central Science · doi:10.1021/acscentsci.0c00549 · Cited by 470
Mechanochemistry: New Tools to Navigate the Uncharted Territory of “Impossible” Reactions
Cuccu, F., De Luca, L., Delogu, F., Colacino, E., Solin, N., Mocci, R., & Porcheddu, A. (2022) · ChemSusChem · doi:10.1002/cssc.202200362 · Cited by 339
Cross-Electrophile Coupling: Principles, Methods, and Applications in Synthesis
Ehehalt, L. E., Beleh, O. M., Priest, I. C., Mouat, J. M., Olszewski, A. K., Ahern, B. N., Cruz, A. R., Chi, B. K., Castro, A. J., Kang, K., et al. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.4c00524 · Cited by 312
Metadata
- Authors
- Constantin, T., Zanini, M., Regni, A., Sheikh, N. S., Juliá, F., & Leonori, D.
- Venue
- Science
- Published
- 2020-02-28
- Volume
- 367
- Issue
- 6481
- Pages
- 1021-1026
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W3005577464
- Cited by
- 581
- References
- 5
- FWCI
- 25.65
- Type
- journal article
- Language
- en
- Open access
- green
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