The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
High-entropy mechanism to boost ionic conductivity
Abstract
Advances in solid-state batteries have primarily been driven by the discovery of superionic conducting structural frameworks that function as solid electrolytes. We demonstrate the ability of high-entropy metal cation mixes to improve ionic conductivity in a compound, which leads to less reliance on specific chemistries and enhanced synthesizability. The local distortions introduced into high-entropy materials give rise to an overlapping distribution of site energies for the alkali ions so that they can percolate with low activation energy. Experiments verify that high entropy leads to orders-of-magnitude higher ionic conductivities in lithium (Li)–sodium (Na) superionic conductor (Li-NASICON), sodium NASICON (Na-NASICON), and Li-garnet structures, even at fixed alkali content. We provide insight into selecting the optimal distortion and designing high-entropy superionic conductors across the vast compositional space.
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Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Oses, C., Toher, C., & Curtarolo, S. (2020) · Nature Reviews Materials · doi:10.1038/s41578-019-0170-8 · Cited by 2,081
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High-entropy materials for energy and electronic applications
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Huang, J., Wu, K., Xu, G., Wu, M., Dou, S., & Wu, C. (2023) · Chemical Society Reviews · doi:10.1039/d2cs01029a · Cited by 304
The promise of high-entropy materials for high-performance rechargeable Li-ion and Na-ion batteries
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Metadata
- Authors
- Zeng, Y., Ouyang, B., Liu, J., Byeon, Y.-W., Cai, Z., Miara, L. J., Wang, Y., & Ceder, G.
- Venue
- Science
- Published
- 2022-12-23
- Volume
- 378
- Issue
- 6626
- Pages
- 1320-1324
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W4312090027
- Cited by
- 558
- References
- 2
- FWCI
- 28.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zeng, Y., Ouyang, B., Liu, J., Byeon, Y.-W., Cai, Z., Miara, L. J., Wang, Y., & Ceder, G. (2022). High-entropy mechanism to boost ionic conductivity. Science. https://doi.org/10.1126/science.abq1346
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