The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Size of cerium dioxide support nanocrystals dictates reactivity of highly dispersed palladium catalysts
Open accessAbstract
The catalytic performance of heterogeneous catalysts can be tuned by modulation of the size and structure of supported transition metals, which are typically regarded as the active sites. In single-atom metal catalysts, the support itself can strongly affect the catalytic properties. Here, we demonstrate that the size of cerium dioxide (CeO 2 ) support governs the reactivity of atomically dispersed palladium (Pd) in carbon monoxide (CO) oxidation. Catalysts with small CeO 2 nanocrystals (~4 nanometers) exhibit unusually high activity in a CO-rich reaction feed, whereas catalysts with medium-size CeO 2 (~8 nanometers) are preferred for lean conditions. Detailed spectroscopic investigations reveal support size–dependent redox properties of the Pd-CeO 2 interface.
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Cites
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
Herzing, A. A., Kiely, C. J., Carley, A. F., Landon, P., & Hutchings, G. J. (2008) · Science · doi:10.1126/science.1159639 · Cited by 1,530
Cited by
Song, H., Yong, X., Waterhouse, G. I. N., Yu, J., Wang, H., Cai, J., Tang, Z., Yang, B., Chang, J., & Lu, S. (2024) · ACS Catalysis · doi:10.1021/acscatal.3c06182 · Cited by 280
Zhao, C., Wen, M., Wang, Q., Ouyang, W., Xu, D., Jia, Z., Zheng, Y., Xi, T., & Sheng, L. (2025) · Journal of Materials Science & Technology · doi:10.1016/j.jmst.2025.01.016 · Cited by 76
Wang, L., Zhen, S., Nallathambi, V., Wang, C., Shi, X., Lu, N., Hübner, R., Eychmüller, A., Reichenberger, S., Gault, B., et al. (2026) · Journal of the American Chemical Society · doi:10.1021/jacs.6c02377 · Cited by 1
Metadata
- Authors
- Muravev, V., Parastaev, A., van den Bosch, Y., Ligt, B., Claes, N., Bals, S., Kosinov, N., & Hensen, E. J. M.
- Venue
- Science
- Published
- 2023-06-16
- Volume
- 380
- Issue
- 6650
- Pages
- 1174-1179
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W4380763061
- Cited by
- 328
- References
- 1
- FWCI
- 23.08
- Type
- journal article
- Language
- en
- Open access
- green
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- Muravev, V., Parastaev, A., van den Bosch, Y., Ligt, B., Claes, N., Bals, S., Kosinov, N., & Hensen, E. J. M. (2023). Size of cerium dioxide support nanocrystals dictates reactivity of highly dispersed palladium catalysts. Science. https://doi.org/10.1126/science.adf9082
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