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Cited by 328

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Size of cerium dioxide support nanocrystals dictates reactivity of highly dispersed palladium catalysts

Open access
Muravev, Valery, Parastaev, Alexander, van den Bosch, Yannis, Ligt, Bianca, Claes, Nathalie, Bals, Sara, Kosinov, Nikolay, Hensen, Emiel J. M.·2023·Science

Abstract

The catalytic performance of heterogeneous catalysts can be tuned by modulation of the size and structure of supported transition metals, which are typically regarded as the active sites. In single-atom metal catalysts, the support itself can strongly affect the catalytic properties. Here, we demonstrate that the size of cerium dioxide (CeO 2 ) support governs the reactivity of atomically dispersed palladium (Pd) in carbon monoxide (CO) oxidation. Catalysts with small CeO 2 nanocrystals (~4 nanometers) exhibit unusually high activity in a CO-rich reaction feed, whereas catalysts with medium-size CeO 2 (~8 nanometers) are preferred for lean conditions. Detailed spectroscopic investigations reveal support size–dependent redox properties of the Pd-CeO 2 interface.

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Crossref · 10.1126/science.adf9082

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Metadata

Authors
Muravev, V., Parastaev, A., van den Bosch, Y., Ligt, B., Claes, N., Bals, S., Kosinov, N., & Hensen, E. J. M.
Venue
Science
Published
2023-06-16
Volume
380
Issue
6650
Pages
1174-1179
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W4380763061
Cited by
328
References
1
FWCI
23.08
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Size of cerium dioxide support nanocrystals dictates reactivity of highly dispersed palladium catalysts. https://app.cochat.ai/papers/10.1126/science.adf9082
The paper
Muravev, V., Parastaev, A., van den Bosch, Y., Ligt, B., Claes, N., Bals, S., Kosinov, N., & Hensen, E. J. M. (2023). Size of cerium dioxide support nanocrystals dictates reactivity of highly dispersed palladium catalysts. Science. https://doi.org/10.1126/science.adf9082

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.