The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Enantioselective electrochemical cobalt-catalyzed aryl C–H activation reactions
Open accessAbstract
Enantioselective redox transformations typically rely on costly transition metals as catalysts and often stoichiometric amounts of chemical redox agents as well. Electrocatalysis represents a more sustainable alternative, in particular through the use of the hydrogen evolution reaction (HER) in place of a chemical oxidant. In this work, we describe strategies for HER-coupled enantioselective aryl carbon-hydrogen bond (C–H) activation reactions using cobalt in place of a precious metal catalyst for the asymmetric oxidation. Thus, highly enantioselective carbon-hydrogen and nitrogen-hydrogen (C–H and N–H) annulations of carboxylic amides were achieved, which gave access to point and axially chiral compounds. Furthermore, the cobalt-mediated electrocatalysis enabled the preparation of various phosphorus (P)–stereogenic compounds by selective desymmetrization through dehydrogenative C–H activation reactions.
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Cited by
Electrochemical hydrogenation and oxidation of organic species involving water
Liu, C., Chen, F., Zhao, B.-H., Wu, Y., & Zhang, B. (2024) · Nature Reviews Chemistry · doi:10.1038/s41570-024-00589-z · Cited by 269
Metadata
- Authors
- von Münchow, T., Dana, S., Xu, Y., Yuan, B., & Ackermann, L.
- Venue
- Science
- Published
- 2023-03-10
- Volume
- 379
- Issue
- 6636
- Pages
- 1036-1042
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W4323811023
- Cited by
- 299
- References
- 35
- FWCI
- 28.96
- Type
- journal article
- Language
- en
- Open access
- green
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