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Black hole chemistry
Abstract
The mass of a black hole has traditionally been identified with its energy. We describe a new perspective on black hole thermodynamics, one that identifies the mass of a black hole with chemical enthalpy, and the cosmological constant as thermodynamic pressure. This leads to an understanding of black holes from the viewpoint of chemistry, in terms of concepts such as Van der Waals fluids, reentrant phase transitions, and triple points. Both charged and rotating black holes exhibit novel chemical-type phase behaviour, hitherto unseen.
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Allowing for the cosmological constant to be a dynamical pressure gives the thermodynamics of anti-de Sitter black holes a richer structure than their asymptotically flat counterparts; behaving as Van der Waals fluids, polymers, and allowing for the construction of black hole heat engines.
“Glossing over the details, allowing for the cosmological constant to be a dynamical pressure has the thermodynamics of anti-de Sitter black holes, in particular, acquire a richer structure than their asymptotically flat counterparts; behaving as Van der Waals fluids [145,146], polymers [147], and allowing for the construction of black hole heat engines [148].”
From Three-Dimensional Quantum Black Holes: A Primer (2024) · cites this paper as [147]
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Thermodynamics of black holes in anti-de Sitter space
Hawking, S. W., & Page, D. N. (1983) · Communications in Mathematical Physics · doi:10.1007/bf01208266 · Cited by 3,045
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Three-Dimensional Quantum Black Holes: A Primer
Panella, E., Pedraza, J. F., & Svesko, A. (2024) · Universe · doi:10.3390/universe10090358 · Cited by 24
Vacuum decay and bubble nucleation in the anti-de Sitter black holes
Li, R., & Wang, J. (2022) · Journal of High Energy Physics · doi:10.1007/jhep09(2022)151 · Cited by 2
Metadata
- Authors
- Kubizňák, D., & Mann, R. B.
- Affiliations
- Perimeter Institute for Theoretical Physics, 31 Caroline St. N., Waterloo, ON N2L 2Y5, Canada.
- Department of Physics and Astronomy, University of Waterloo, 200 University Ave., Waterloo, ON N2L 3G1, Canada.
- Venue
- Canadian Journal of Physics
- Publisher
- Canadian Science Publishing
- Published
- 2015-09
- Volume
- 93
- Issue
- 9
- Pages
- 999-1002
- ISSN
- 0008-4204
- 1208-6045
- Cited by
- 224
- References
- 1
- Language
- en
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