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Structural Study on Cubic–Tetragonal Transition of CH3NH3PbI3
Abstract
The cubic–tetragonal phase transition of CH 3 NH 3 PbI 3 was investigated by single crystal X-ray diffractometry. The crystal structure was refined at five temperatures in the teragonal phase. The PbI 6 octahedron rorates around the c -axis alternatively to construct the SrTiO 3 -type tetragonal structure. A methylammonium ion is partially orderd; 24 disordered states in the cubic phase are reduced to 8. With decreasing temperature, the rotation angle of the octahedron increases monotonically, which indicates it is an order parameter of the cubic-tetragonal transition.
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Citations
Cited by
Park, N.-G. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz400892a · Cited by 1,382
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Filip, M. R., Eperon, G. E., Snaith, H. J., & Giustino, F. (2014) · Nature Communications · doi:10.1038/ncomms6757 · Cited by 1,081
Jinnouchi, R., Lahnsteiner, J., Karsai, F., Kresse, G., & Bokdam, M. (2019) · Physical Review Letters · doi:10.1103/physrevlett.122.225701 · Cited by 635
Almora, O., Zarazua, I., Mas-Marza, E., Mora-Sero, I., Bisquert, J., & Garcia-Belmonte, G. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b00480 · Cited by 503
Interfacial Residual Stress Relaxation in Perovskite Solar Cells with Improved Stability
Wang, H., Zhu, C., Liu, L., Ma, S., Liu, P., Wu, J., Shi, C., Du, Q., Hao, Y., Xiang, S., et al. (2019) · Advanced Materials · doi:10.1002/adma.201904408 · Cited by 499
Metadata
- Authors
- Kawamura, Y., Mashiyama, H., & Hasebe, K.
- Venue
- Journal of the Physical Society of Japan
- Publisher
- Physical Society of Japan
- Published
- 2002-07-15
- Volume
- 71
- Issue
- 7
- Pages
- 1694-1697
- ISSN
- 0031-9015 (ISSN-L)
- 1347-4073
- OpenAlex
- W2051840604
- Cited by
- 510
- References
- 0
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kawamura, Y., Mashiyama, H., & Hasebe, K. (2002). Structural Study on Cubic–Tetragonal Transition of CH3NH3PbI3. Journal of the Physical Society of Japan. https://doi.org/10.1143/jpsj.71.1694
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