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Diffusion-Controlled Reactions
Abstract
It is apparent that the kinetic rate kD influences the effective rate of reaction and that in certain circumstances (kr � kr) it becomes the rate limiting step [keff = kD]. Accordingly, the rate coefficient kD' which describes the mass transport rate at which reactants encounter each other, is of central concern to solution kineticists. There is little doubt that the subject of diffusion-controlled reactions has broad application beyond this prototype example. Diffusion-controlled reactions play a prominent role in heterogeneous catalysis (after all, the perfeot catalyst leads to mass transport limitations), polymer chain growth kinetics, colloid or crystal growth, and biophysical chemistry.
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Citations
Cited by
Reaction-rate theory: fifty years after Kramers
Hänggi, P., Talkner, P., & Borkovec, M. (1990) · Reviews of Modern Physics · doi:10.1103/revmodphys.62.251 · Cited by 6,154
Brownian dynamics simulation of diffusion-influenced bimolecular reactions
Northrup, S. H., Allison, S. A., & McCammon, J. A. (1984) · The Journal of Chemical Physics · doi:10.1063/1.446900 · Cited by 356
Computer-Aided Molecular Design
McCammon, J. A. (1987) · Science · doi:10.1126/science.3310236 · Cited by 324
Rate processes on fractals: Theory, simulations, and experiments
Kopelman, R. (1986) · Journal of Statistical Physics · doi:10.1007/bf01010846 · Cited by 314
Simulation of the diffusional association of barnase and barstar
Gabdoulline, R. R., & Wade, R. C. (1997) · Biophysical Journal · doi:10.1016/s0006-3495(97)78838-6 · Cited by 275
Metadata
- Authors
- Calef, D. F., & Deutch, J. M.
- Venue
- Annual Review of Physical Chemistry
- Publisher
- Annual Reviews
- Published
- 1983-10
- Volume
- 34
- Issue
- 1
- Pages
- 493-524
- ISSN
- 0066-426X (ISSN-L)
- 1545-1593
- OpenAlex
- W2175900701
- Cited by
- 390
- References
- 0
- FWCI
- 6.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- Calef, D. F., & Deutch, J. M. (1983). Diffusion-Controlled Reactions. Annual Review of Physical Chemistry. https://doi.org/10.1146/annurev.pc.34.100183.002425
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
