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STARK SPECTROSCOPY: Applications in Chemistry, Biology, and Materials Science
Abstract
▪ Abstract Stark spectroscopy has been applied to a wide range of molecular systems and materials. A generally useful method for obtaining electronic and vibrational Stark spectra that does not require sophisticated equipment is described. By working with frozen glasses it is possible to study nearly any molecular system, including ions and proteins. Quantitative analysis of the spectra provides information on the change in dipole moment and polarizability associated with a transition. The change in dipole moment reflects the degree of charge separation for a transition, a quantity of interest to a variety of fields. The polarizability change describes the sensitivity of a transition to an electrostatic field such as that found in a protein or an ordered synthetic material. Applications to donor-acceptor polyenes, transition metal complexes (metal-to-ligand and metal-to-metal mixed valence transitions), and nonphotosynthetic biological systems are reviewed.
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Citations
Cited by
Water Dynamics in the Hydration Shells of Biomolecules
Laage, D., Elsaesser, T., & Hynes, J. T. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00765 · Cited by 913
Vibrational Spectroscopic Map, Vibrational Spectroscopy, and Intermolecular Interaction
Baiz, C. R., Błasiak, B., Bredenbeck, J., Cho, M., Choi, J.-H., Corcelli, S. A., Dijkstra, A. G., Feng, C.-J., Garrett-Roe, S., Ge, N.-H., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00813 · Cited by 412
Gonzalez-Diaz, H., Arrasate, S., Gomez-SanJuan, A., Sotomayor, N., Lete, E., Besada-Porto, L., & Ruso, J. (2013) · Current Topics in Medicinal Chemistry · doi:10.2174/1568026611313140011 · Cited by 101
Metadata
- Authors
- Bublitz, G. U., & Boxer, S. G.
- Venue
- Annual Review of Physical Chemistry
- Publisher
- Annual Reviews
- Published
- 1997-10
- Volume
- 48
- Issue
- 1
- Pages
- 213-242
- ISSN
- 0066-426X (ISSN-L)
- 1545-1593
- OpenAlex
- W2170317460
- Cited by
- 620
- References
- 0
- FWCI
- 1.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: STARK SPECTROSCOPY: Applications in Chemistry, Biology, and Materials Science. https://app.cochat.ai/papers/10.1146/annurev.physchem.48.1.213
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- Bublitz, G. U., & Boxer, S. G. (1997). STARK SPECTROSCOPY: Applications in Chemistry, Biology, and Materials Science. Annual Review of Physical Chemistry. https://doi.org/10.1146/annurev.physchem.48.1.213
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
