The DOI matches its Crossref record; 65 of the 65 references it cites were found in a registry or an index.
PROTON-COUPLED ELECTRON TRANSFER
Abstract
▪ Abstract Proton-coupled electron transfer (PCET) is an important mechanism for charge transfer in a wide variety of systems including biology- and materials-oriented venues. We review several areas where the transfer of an electron and proton is tightly coupled and discuss model systems that can provide an experimental basis for a test of PCET theory. In a PCET reaction, the electron and proton may transfer consecutively (ET/PT) or concertedly (ETPT). The distinction between these processes is formulated, and rate-constant expressions for the two reaction channels are presented. Methods for the evaluation of these rate constants are discussed that are based on dielectric continuum theory. Electron donor hydrogen-bonded-interface electron acceptor systems displaying PCET reactivity are presented, and the rate-constant expressions corresponding to the ETPT and ET/PT channels for several model reaction complexes are evaluated.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Electron transfers in chemistry and biology
Marcus, R. A., & Sutin, N. (1985) · Biochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics · doi:10.1016/0304-4173(85)90014-x · Cited by 8,050
On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. I
Marcus, R. A. (1956) · The Journal of Chemical Physics · doi:10.1063/1.1742723 · Cited by 6,081
Coupling of phosphorylation to electron and hydrogen transfer by a chemi-osmotic type of mechanism
MITCHELL, P. (1961) · Nature · doi:10.1038/191144a0 · Cited by 4,704
Warshel, A., & Levitt, M. (1976) · Journal of Molecular Biology · doi:10.1016/0022-2836(76)90311-9 · Cited by 4,479
Chemical and Electrochemical Electron-Transfer Theory
Marcus, R. A. (1964) · Annual Review of Physical Chemistry · doi:10.1146/annurev.pc.15.100164.001103 · Cited by 4,408
Classical Electrostatics in Biology and Chemistry
Honig, B., & Nicholls, A. (1995) · Science · doi:10.1126/science.7761829 · Cited by 2,879
Zinc Finger-DNA Recognition: Crystal Structure of a Zif268-DNA Complex at 2.1 Å
Pavletich, N. P., & Pabo, C. O. (1991) · Science · doi:10.1126/science.2028256 · Cited by 2,061
Anoxygenic Photosynthetic Bacteria
(1995) · Advances in Photosynthesis and Respiration · doi:10.1007/0-306-47954-0 · Cited by 1,902
Photochromism : molecules and systems
Dürr, H., & Bouas‐Laurent, H. (2003) · Cited by 1,708
Oxygenic Photosynthesis: The Light Reactions
(1996) · Advances in Photosynthesis and Respiration · doi:10.1007/0-306-48127-8 · Cited by 1,329
Cited by
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Proton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
Stubbe, J., Nocera, D. G., Yee, C. S., & Chang, M. C. Y. (2003) · Chemical Reviews · doi:10.1021/cr020421u · Cited by 823
Self-citationBase stacking controls excited-state dynamics in A·T DNA
Crespo-Hernández, C. E., Cohen, B., & Kohler, B. (2005) · Nature · doi:10.1038/nature03933 · Cited by 461
Constrained Density Functional Theory and Its Application in Long-Range Electron Transfer
Wu, Q., & Van Voorhis, T. (2006) · Journal of Chemical Theory and Computation · doi:10.1021/ct0503163 · Cited by 323
Metadata
- Authors
- Cukier, R. I., & Nocera, D. G.
- Venue
- Annual Review of Physical Chemistry
- Publisher
- Annual Reviews
- Published
- 1998-10
- Volume
- 49
- Issue
- 1
- Pages
- 337-369
- ISSN
- 0066-426X (ISSN-L)
- 1545-1593
- OpenAlex
- W2614884730
- Cited by
- 854
- References
- 65
- FWCI
- 2.18
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: PROTON-COUPLED ELECTRON TRANSFER. https://app.cochat.ai/papers/10.1146/annurev.physchem.49.1.337
- The paper
- Cukier, R. I., & Nocera, D. G. (1998). PROTON-COUPLED ELECTRON TRANSFER. Annual Review of Physical Chemistry. https://doi.org/10.1146/annurev.physchem.49.1.337
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
