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EXCITONS IN CONJUGATED OLIGOMER AGGREGATES, FILMS, AND CRYSTALS
Abstract
▪ Abstract Recent experimental and theoretical investigations of excitons in conjugated oligomer nanoaggregates, thin films, and crystals are reviewed. The review focuses on the technologically important unsubstituted oligo-phenylene vinylenes (OPVn) and oligo-thiophenes (OTn), which exhibit side-by-side herringbone crystal packing. Many of the salient photophysical properties displayed by OPVn and OTn solid phases, including the large Davydov splitting, the rich variety of peaks due to vibronic coupling in both absorption and emission, and the unusual behavior of the emission origin, are accounted for in a model including excitonic coupling between molecules, linear exciton-phonon coupling, and disorder.
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Cites
Absence of Diffusion in Certain Random Lattices
Anderson, P. W. (1958) · Physical Review · doi:10.1103/physrev.109.1492 · Cited by 12,468
Cited by
Luminescent metal–organic frameworks
Allendorf, M. D., Bauer, C. A., Bhakta, R. K., & Houk, R. J. T. (2009) · Chemical Society Reviews · doi:10.1039/b802352m · Cited by 4,960
Hestand, N. J., & Spano, F. C. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00581 · Cited by 1,904
Self-citationThe Spectral Signatures of Frenkel Polarons in H- and J-Aggregates
Spano, F. C. (2010) · Accounts of Chemical Research · doi:10.1021/ar900233v · Cited by 1,726
Self-citationHestand, N. J., & Spano, F. C. (2017) · Accounts of Chemical Research · doi:10.1021/acs.accounts.6b00576 · Cited by 711
Self-citationKim, F. S., Ren, G., & Jenekhe, S. A. (2011) · Chemistry of Materials · doi:10.1021/cm102772x · Cited by 664
Metadata
- Authors
- Spano, F. C.
- Venue
- Annual Review of Physical Chemistry
- Publisher
- Annual Reviews
- Published
- 2006-05-01
- Volume
- 57
- Issue
- 1
- Pages
- 217-243
- ISSN
- 0066-426X (ISSN-L)
- 1545-1593
- OpenAlex
- W2140962873
- Cited by
- 343
- References
- 1
- FWCI
- 1.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- Spano, F. C. (2006). EXCITONS IN CONJUGATED OLIGOMER AGGREGATES, FILMS, AND CRYSTALS. Annual Review of Physical Chemistry. https://doi.org/10.1146/annurev.physchem.57.032905.104557
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