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The Mechanisms of Lithium and Sodium Insertion in Carbon Materials
Open accessAbstract
In this paper, we compare the interactions of lithium and sodium with a range of carbon materials in electrochemical cells. Through wide angle in situ X-ray scattering studies, we demonstrate that both lithium and sodium can be inserted into the interlayer space in disordered carbon materials. This insertion process is accompanied by an increase in the interlayer spacing in these materials. Small-angle in situ scattering studies are presented to clearly show the insertion of lithium and sodium into nanopores within disordered hard carbons. We also show that very little, if any, sodium can be inserted into graphitic materials in contrast to the large capacity seen for lithium insertion. © 2001 The Electrochemical Society. All rights reserved.
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Cited by
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Saurel, D., Orayech, B., Xiao, B., Carriazo, D., Li, X., & Rojo, T. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201703268 · Cited by 668
Reduced graphene oxide with superior cycling stability and rate capability for sodium storage
Wang, Y.-X., Chou, S.-L., Liu, H.-K., & Dou, S.-X. (2013) · Carbon · doi:10.1016/j.carbon.2013.01.064 · Cited by 561
Revealing the Intercalation Mechanisms of Lithium, Sodium, and Potassium in Hard Carbon
Alvin, S., Cahyadi, H. S., Hwang, J., Chang, W., Kwak, S. K., & Kim, J. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202000283 · Cited by 452
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Metadata
- Authors
- Stevens, D. A., & Dahn, J. R.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2001
- Volume
- 148
- Issue
- 8
- Pages
- A803
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2169911761
- Cited by
- 1,499
- References
- 0
- FWCI
- 1.67
- Type
- journal article
- Language
- en
- Open access
- bronze
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