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A Novel Concept for the Synthesis of an Improved LiFePO[sub 4] Lithium Battery Cathode
Abstract
This paper describes the synthesis and the properties of a kinetically improved cathode material. The novel aspect of the synthesis is based on a critical step involving the dispersion of metal ( e.g. , copper or silver) at a very low concentration (1 wt %). This metal addition does not affect the structure of the cathode but considerably improves its kinetics in terms of capacity delivery and cycle life. Such an enhancement of the electrochemical properties has been ascribed to a reduction of the particle size and to an increase of the bulk intra- and interparticle electronic conductivity of both effects being promoted by the finely dispersed metal powders. This improved conductivity favors the response of thus substantiating its interest as new cathode for advanced lithium ion batteries. © 2002 The Electrochemical Society. All rights reserved.
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Cited by
Development and challenges of LiFePO4cathode material for lithium-ion batteries
Yuan, L.-X., Wang, Z.-H., Zhang, W.-X., Hu, X.-L., Chen, J.-T., Huang, Y.-H., & Goodenough, J. B. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00029a · Cited by 1,301
Modeling of Lithium-Ion Battery Degradation for Cell Life Assessment
Xu, B., Oudalov, A., Ulbig, A., Andersson, G., & Kirschen, D. S. (2018) · IEEE Transactions on Smart Grid · doi:10.1109/tsg.2016.2578950 · Cited by 1,162
Developments in Nanostructured Cathode Materials for High‐Performance Lithium‐Ion Batteries
Wang, Y., & Cao, G. (2008) · Advanced Materials · doi:10.1002/adma.200702242 · Cited by 1,116
Recent progress in cathode materials research for advanced lithium ion batteries
Xu, B., Qian, D., Wang, Z., & Meng, Y. S. (2012) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2012.05.003 · Cited by 834
Guo, Y. ‐., Hu, Y. ‐., Sigle, W., & Maier, J. (2007) · Advanced Materials · doi:10.1002/adma.200602828 · Cited by 601
Metadata
- Authors
- Croce, F., D’ Epifanio, A., Hassoun, J., Deptula, A., Olczac, T., & Scrosati, B.
- Venue
- Electrochemical and Solid-State Letters
- Publisher
- The Electrochemical Society
- Published
- 2002
- Volume
- 5
- Issue
- 3
- Pages
- A47
- ISSN
- 1099-0062 (ISSN-L)
- OpenAlex
- W2088695076
- Cited by
- 571
- References
- 0
- FWCI
- 28.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Croce, F., D’ Epifanio, A., Hassoun, J., Deptula, A., Olczac, T., & Scrosati, B. (2002). A Novel Concept for the Synthesis of an Improved LiFePO[sub 4] Lithium Battery Cathode. Electrochemical and Solid-State Letters. https://doi.org/10.1149/1.1449302
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
