Cited by 16Fuel Cells and Related MaterialsAdvancements in Solid Oxide Fuel CellsElectrocatalysts for Energy Conversion

Sulfonimide Polyphosphazene-Based H[sub 2]/O[sub 2] Fuel Cells

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Chalkova, Elena, Zhou, Xiangyang, Ambler, Catherine, Hofmann, Michael A., Weston, Jamie A., Allcock, Harry R., Lvov, Serguei N.·2002·Electrochemical and Solid-State Letters

Abstract

Sulfonimide-functionalized polyphosphazenes have been investigated as polymer electrolyte membranes for use in an fuel cell. A sulfonimide polyphosphazene-based membrane electrode assembly (MEA) and a Nafion-based MEA with similar catalyst loadings were fabricated and tested within a fuel cell system. The maximum power density for the sulfonimide polyphosphazene MEA was at and 22°C, and reached at at 80°C. The performance of the sulfonimide polyphosphazene-based fuel cell was found to be comparable to that of the Nafion-based fuel cell. © 2002 The Electrochemical Society. All rights reserved.

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  • Allcock et al. synthesized polyphosphazenes with phosphonic or sulfonimide groups, where the former exhibited low methanol permeability, although no DMFC data were collected.

    “Allcock et al. [26][27][28] synthesized polyphosphazenes with phosphonic or sulfonimide groups, where the former exhibited low methanol permeability, although no DMFC data were collected.”

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References 17 · Cited by 16

Research works printed but not linked: 4

  1. Y. Si, J-C. Lin, H. R. Kunz, and J. M. Fenton, Abstract 358, The Electrochemical Society Meeting Abstracts, Vol. 2001-2, San Francisco, CA, Sept 2-7, 2001.
  2. J. R. Atkins, S. E. Creager, B. H. Thomas, and D. D. DesMarteau, Abstract 111, The Electrochemical Society Meeting Abstracts, Vol. 2001-1, Washington, DC, March 25-29, 2001.
  3. Y. S. Kim, F. Wang, M. Hickner, T. A. Zawodzinski, and J. E. McGrath, Abstract 311-PMSE, The American Chemical Society Abstracts, Vol. 222 ͑2001͒.
  4. X. Y. Zhou, M. A. Hofmann, J. A. Weston, E. Chalkova, H. R. Allcock, and S. N. Lvov, in Direct Methanol Fuel Cells, S. Narayanan, T. Zawodzinski, and S. Got- tesfeld, Editors, PV 2001-4, p. 34, The Electrochemical Society Proceedings Series, Pennington, NJ ͑2001͒.

Authors
Chalkova, E., Zhou, X., Ambler, C., Hofmann, M. A., Weston, J. A., Allcock, H. R., & Lvov, S. N.
Affiliations
  • Energy Institute (GB)
  • Pennsylvania State University (US)
Venue
Electrochemical and Solid-State Letters
Published
2002
Volume
5
Issue
10
Pages
A221
ISSN
1099-0062 (ISSN-L)
OpenAlex
W2278782680
Cited by
16
References
17
Citations by year
2025: 1 · 2020: 1 · 2017: 1 · 2015: 1 · 2014: 1 · 2013: 1 · 2012: 1
FWCI
1.05
Type
journal article
Language
en
Open access
Locations
Electrochemical and Solid-State Letters (publishedVersion)
Funders
U.S. Department of Energy (FC3601GO11085)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
  • Physical Sciences › Materials Science › Materials Chemistry › Advancements in Solid Oxide Fuel Cells
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Keywords
proton exchange membrane fuel cells, hydrogen peroxide fuel cells, polymer electrolyte membranes, membrane electrode assembly, Nafion comparison, power density, temperature dependence

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