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Li-Storage via Heterogeneous Reaction in Selected Binary Metal Fluorides and Oxides
Abstract
We report on electrochemical reactions of a variety of metal fluorides ( TiF 3 , VF 3 , MnF 2 , FeF 2 , CoF 2 , NiF 2 , CuF 2 , CaF 2 , BaF 2 ) , metal oxides (TiO, TiO 2 , VO 2 , V 2 O 3 , V 2 O 5 , NbO, NbO 2 , Cr 2 O 3 , RuO 2 , MoO 3 ) , TiS 2 , and TiN with lithium in nonaqueous lithium cells over a wide voltage range (0.02-4.3 V) at room temperature. In most cases, deep Li uptake occurs via heterogeneous reaction resulting in transformation of MX m ( M = transition metal ; X = F or O or S or N) into a nanocrystalline or amorphous LiX m / n / M composite from which Li can be extracted under restoration of the MX m phase. Thermodynamic and kinetic aspects, especially overpotential and its possible origins for both Li uptake and Li extraction processes, are discussed. © 2004 The Electrochemical Society. All rights reserved.
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Cited by
Cabana, J., Monconduit, L., Larcher, D., & Palacín, M. R. (2010) · Advanced Materials · doi:10.1002/adma.201000717 · Cited by 2,361
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Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Thermodynamic analysis on energy densities of batteries
Zu, C.-X., & Li, H. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00777c · Cited by 911
Self-citationElectrode Degradation in Lithium-Ion Batteries
Pender, J. P., Jha, G., Youn, D. H., Ziegler, J. M., Andoni, I., Choi, E. J., Heller, A., Dunn, B. S., Weiss, P. S., Penner, R. M., et al. (2020) · ACS Nano · doi:10.1021/acsnano.9b04365 · Cited by 873
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Metadata
- Authors
- Li, H., Balaya, P., & Maier, J.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2004
- Volume
- 151
- Issue
- 11
- Pages
- A1878
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2071933281
- Cited by
- 590
- References
- 0
- FWCI
- 8.17
- Type
- journal article
- Language
- en
- Open access
- closed
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