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Iron(II) Catalysis of the Mineralization of Aniline Using a Carbon‐PTFE O 2 ‐ Fed Cathode
Open accessAbstract
Mineralization of aniline in acidic solution (pH 3.0) has been studied using an undivided cell with a carbon‐polytetrafluoroethylene cathode which continuously electrogenerates operating at constant current. A electrode or a Pt sheet was employed as the anode. While anodic destruction of aniline yields poor mineralization, addition of iron(II) to the solution causes a notable increase in its mineralization rate. In the so‐called electro‐Fenton process, the main oxidizing agent is which can be produced at the anode reaction layer by oxidation of water and also in the bulk solution via Fenton's reaction between and electrogenerated . A faster and complete mineralization of the pollutant in the presence of iron(II) can be easily achieved by the photoelectro‐Fenton process in which the solution is irradiated with UV light of λ max = 360 nm during electrolysis. The reactions involved in these processes are discussed.
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Cited by
Electro-Fenton Process and Related Electrochemical Technologies Based on Fenton’s Reaction Chemistry
Brillas, E., Sirés, I., & Oturan, M. A. (2009) · Chemical Reviews · doi:10.1021/cr900136g · Cited by 3,437
Self-citationMartínez-Huitle, C. A., & Ferro, S. (2006) · Chem. Soc. Rev. · doi:10.1039/b517632h · Cited by 1,840
Deng, F., Olvera-Vargas, H., Zhou, M., Qiu, S., Sirés, I., & Brillas, E. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00684 · Cited by 409
Self-citationElectro-Fenton degradation of synthetic dyes
Panizza, M., & Cerisola, G. (2009) · Water Research · doi:10.1016/j.watres.2008.10.028 · Cited by 377
Electrochemical technologies for wastewater treatment and resource reclamation
Feng, Y., Yang, L., Liu, J., & Logan, B. E. (2016) · Environmental Science: Water Research & Technology · doi:10.1039/c5ew00289c · Cited by 371
Metadata
- Authors
- Brillas, E., Mur, E., & Casado, J.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1996-03-01
- Volume
- 143
- Issue
- 3
- Pages
- L49-L53
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2039635731
- Cited by
- 182
- References
- 0
- FWCI
- 5.36
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Brillas, E., Mur, E., & Casado, J. (1996). Iron(II) Catalysis of the Mineralization of Aniline Using a Carbon‐PTFE O 2 ‐ Fed Cathode. Journal of The Electrochemical Society. https://doi.org/10.1149/1.1836528
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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