The DOI matches its Crossref record.
Revised Pourbaix Diagrams for Copper at 25 to 300°C
Open accessAbstract
The Pourbaix diagrams (potential‐pH diagrams) for copper at 25 to 300°C have been revised. Extrapolation of thermochemical data to elevated temperatures has been performed with the revised model of Helgeson‐Kirkham‐Flowers, which also allows uncharged aqueous complexes, such as CuOH(aq) and , to be handled. Calculated high temperature thermodynamic data have been fitted against experimental data at elevated temperature. The hydrolysis of copper(I) and (II) is included with two and four hydroxide complexes, respectively. The Pourbaix diagrams show that the oxides and CuO(cr)) are stable at 25 to 200°C at 10 −6 mol kg −1 of dissolved species, and at 300°C only CuO is stable. The oxides are stable at 25°C at 10 −8 mol kg −1 , but at 100 to 300°C no solid compound is stable.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Ren, D., Deng, Y., Handoko, A. D., Chen, C. S., Malkhandi, S., & Yeo, B. S. (2015) · ACS Catalysis · doi:10.1021/cs502128q · Cited by 930
Delmo, E. P., Wang, Y., Song, Y., Zhu, S., Zhang, H., Xu, H., Li, T., Jang, J., Kwon, Y., Wang, Y., et al. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.3c08927 · Cited by 336
Ren, D., Fong, J., & Yeo, B. S. (2018) · Nature Communications · doi:10.1038/s41467-018-03286-w · Cited by 316
Cao, Y., Wang, T., Li, X., Zhang, L., Luo, Y., Zhang, F., Asiri, A. M., Hu, J., Liu, Q., & Sun, X. (2021) · Inorganic Chemistry Frontiers · doi:10.1039/d1qi00124h · Cited by 308
Huang, L.-F., Hutchison, M. J., Santucci, R. J., Scully, J. R., & Rondinelli, J. M. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b02771 · Cited by 300
Metadata
- Authors
- Beverskog, B., & Puigdomenech, I.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1997-10-01
- Volume
- 144
- Issue
- 10
- Pages
- 3476-3483
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2087468688
- Cited by
- 351
- References
- 0
- FWCI
- 0.51
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Revised Pourbaix Diagrams for Copper at 25 to 300°C. https://app.cochat.ai/papers/10.1149/1.1838036
- The paper
- Beverskog, B., & Puigdomenech, I. (1997). Revised Pourbaix Diagrams for Copper at 25 to 300°C. Journal of The Electrochemical Society. https://doi.org/10.1149/1.1838036
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
