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Tuning the Position of the Redox Couples in Materials with NASICON Structure by Anionic Substitution
Abstract
Previous studies on insertion of lithium into rhombohedral forms of and have determined the position of the redox couple to be at 3.6 and 2.8 eV, respectively, below the Fermi level of lithium. Lithium insertion into rhombohedral with NASICON framework exposes the redox couple at 3.3–3.4 eV below the Fermi energy of lithium. Unlike , the insertion of lithium into the structure of is accomplished as a single‐phase solid solution, which makes it attractive as an electrode material for rechargeable lithium batteries.
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Citations
Cited by
Porous electrode materials for lithium-ion batteries–how to prepare them and what makes them special
Vu, A., Qian, Y., & Stein, A. (2012) · Advanced Energy Materials · doi:10.1002/aenm.201200320 · Cited by 719
Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries
Whittingham, M. S., Song, Y., Lutta, S., Zavalij, P. Y., & Chernova, N. A. (2005) · Journal of Materials Chemistry · doi:10.1039/b501961c · Cited by 296
Metadata
- Authors
- Padhi, A. K., Manivannan, V., & Goodenough, J. B.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1998-05-01
- Volume
- 145
- Issue
- 5
- Pages
- 1518-1520
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2006105392
- Cited by
- 211
- References
- 0
- FWCI
- 5.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Tuning the Position of the Redox Couples in Materials with NASICON Structure by Anionic Substitution. https://app.cochat.ai/papers/10.1149/1.1838513
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- Padhi, A. K., Manivannan, V., & Goodenough, J. B. (1998). Tuning the Position of the Redox Couples in Materials with NASICON Structure by Anionic Substitution. Journal of The Electrochemical Society. https://doi.org/10.1149/1.1838513
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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