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PEO-Based Polymer Electrolytes with Ionic Liquids and Their Use in Lithium Metal-Polymer Electrolyte Batteries
Open accessAbstract
The influence of adding the room-temperature ionic liquid (RTIL) -methyl- -propylpyrrolidinium bis(trifluoromethanesulfonyl)imide to polymer electrolytes and the use of these electrolytes in solid-state batteries has been investigated. polymer electrolytes with various mole fractions ( , 1.08, 1.73, 1.94, 2.15, and 3.24) were prepared. The addition of up to a 3.24 mole fraction of the RTIL to electrolytes, corresponding to a RTIL/PEO weight fraction of up to 1.5, resulted in freestanding and highly conductive electrolyte films reaching at . The electrochemical stability of was significantly improved by the addition of LiTFSI. cells using the polymer electrolyte with showed excellent reversible cyclability with a capacity fading of 0.04% per cycle over several hundreds cycles at . The incorporation of the RTIL into lithium metal-polymer electrolyte batteries has resulted in a promising improvement in performance at moderate to low temperatures.
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Citations
Cited by
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
Lithium Batteries: Status, Prospects and Future
Scrosati, B., & Garche, J. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2009.11.048 · Cited by 5,153
Metadata
- Authors
- Shin, J.-H., Henderson, W. A., & Passerini, S.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2005
- Volume
- 152
- Issue
- 5
- Pages
- A978
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W1966713790
- Cited by
- 362
- References
- 0
- FWCI
- 14.62
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: PEO-Based Polymer Electrolytes with Ionic Liquids and Their Use in Lithium Metal-Polymer Electrolyte Batteries. https://app.cochat.ai/papers/10.1149/1.1890701
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- Shin, J.-H., Henderson, W. A., & Passerini, S. (2005). PEO-Based Polymer Electrolytes with Ionic Liquids and Their Use in Lithium Metal-Polymer Electrolyte Batteries. Journal of The Electrochemical Society. https://doi.org/10.1149/1.1890701
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