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Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells

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Ohzuku, Tsutomu, Ueda, Atsushi, Yamamoto, Norihiro·1995·Journal of The Electrochemical Society

Abstract

having a defect spinel‐framework structure was prepared and examined in non‐aqueous lithium cells. (white in color) was reduced to (dark blue) at a voltage of 1.55 V and the reaction was highly reversible. X‐ray diffraction measurements indicated that the lattice dimension did not change during the reaction Since the reaction consists of lithium ion and electron insertion into/extraction from the solid matrix without a noticeable change in lattice dimension, called a zero‐strain insertion reaction, capacity failure due to the damage to the solid matrix was not observed even after 100 cycles. Feasibility of zero‐strain insertion materials for advanced batteries is discussed based on the experimental results.

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Metadata

Authors
Ohzuku, T., Ueda, A., & Yamamoto, N.
Venue
Journal of The Electrochemical Society
Published
1995-05-01
Volume
142
Issue
5
Pages
1431-1435
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
OpenAlex
W1673406831
Cited by
1,940
References
0
FWCI
9.10
Type
journal article
Language
en
Open access
bronze
Licence

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CoChat. (2026). Citation check: Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells. https://app.cochat.ai/papers/10.1149/1.2048592
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Ohzuku, T., Ueda, A., & Yamamoto, N. (1995). Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2048592

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.