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Measurement Models for Electrochemical Impedance Spectroscopy: I . Demonstration of Applicability
Abstract
Use of measurement models is suggested as an intermediate step in the analysis of impedance data. In a manner analogous to the routine use of measurement models in the deconvolution of optical spectra, the measurement model could be used to guide development of physicoelectrochemical models by determining whether a data set is consistent with the Kramers‐Kronig relations, by suggesting a form for the error structure of the data, and by providing an indication of the number and type of physical processes that can be resolved from the data. In this paper, a general measurement model is shown to apply for a wide variety of typical electrochemical impedance spectra. The application of the measurement models as a data filter will be addressed in subsequent papers.
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Cited by
Schichlein, H., Müller, A. C., Voigts, M., Krügel, A., & Ivers-Tiffée, E. (2002) · Journal of Applied Electrochemistry · doi:10.1023/a:1020599525160 · Cited by 668
Impedance Analysis of Electrochemical Systems
Vivier, V., & Orazem, M. E. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00876 · Cited by 615
Self-citationHow the distribution of relaxation times enhances complex equivalent circuit models for fuel cells
Dierickx, S., Weber, A., & Ivers-Tiffée, E. (2020) · Electrochimica Acta · doi:10.1016/j.electacta.2020.136764 · Cited by 281
Metadata
- Authors
- Agarwal, P., Orazem, M. E., & Garcia‐Rubio, L. H.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1992-07-01
- Volume
- 139
- Issue
- 7
- Pages
- 1917-1927
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W1621543113
- Cited by
- 382
- References
- 0
- FWCI
- 5.94
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Measurement Models for Electrochemical Impedance Spectroscopy: I . Demonstration of Applicability. https://app.cochat.ai/papers/10.1149/1.2069522
- The paper
- Agarwal, P., Orazem, M. E., & Garcia‐Rubio, L. H. (1992). Measurement Models for Electrochemical Impedance Spectroscopy: I . Demonstration of Applicability. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2069522
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