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Study of the Kinetics of Hydrogen Evolution Reaction on Nickel‐Zinc Alloy Electrodes
Open accessAbstract
The mechanism and kinetics of the hydrogen evolution reaction were studied in on nickel‐zinc alloy electrodes prepared by electrodeposition at controlled potential. A series of electrodes containing 70 to 28% Ni was prepared. Before the measurements, zinc was leached in alkaline solution. Using the ac impedance technique, it was found that the reaction proceeds via the Volmer‐Heyrovsky mechanism, and the kinetic parameters of the process were determined. With a decrease in the nickel content, the electrode becomes more active, and an increase in the real surface area is observed. The surface morphology was studied using SEM and optical microscopy.
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Citations
Cited by
Experimental study and modeling of impedance of the her on porous Ni electrodes
Hitz, C., & Lasia, A. (2001) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(00)00317-x · Cited by 417
Self-citationLing, C., Shi, L., Ouyang, Y., Chen, Q., & Wang, J. (2016) · Advanced Science · doi:10.1002/advs.201600180 · Cited by 367
Ling, C., Shi, L., Ouyang, Y., & Wang, J. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b03972 · Cited by 355
Renewable electricity storage using electrolysis
Yan, Z., Hitt, J. L., Turner, J. A., & Mallouk, T. E. (2020) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1821686116 · Cited by 248
Zhang, X., Li, Y., Guo, Y., Hu, A., Li, M., Hang, T., & Ling, H. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.09.193 · Cited by 71
Metadata
- Authors
- Chen, L., & Lasia, A.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1991-11-01
- Volume
- 138
- Issue
- 11
- Pages
- 3321-3328
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2039140156
- Cited by
- 276
- References
- 0
- FWCI
- 7.74
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Chen, L., & Lasia, A. (1991). Study of the Kinetics of Hydrogen Evolution Reaction on Nickel‐Zinc Alloy Electrodes. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2085409
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