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Effect of Coprecipitated Metal Ions on the Electrochemistry of Nickel Hydroxide Thin Films: Cyclic Voltammetry in 1M KOH
Open accessAbstract
Binary 9:1 composite hydroxides of nickel with 13 other metals were prepared by cathodic electrocoprecipitation from metal nitrate solutions and characterized by cyclic voltammetry in . Under these conditions, coprecipitated Ce, Fe, and La strongly catalyzed the oxygen evolution reaction. Conversely, Cd, Pb, and Zn poisoned this reaction. The hydrogen evolution reaction was less affected by the coprecipitated metals; Ag and Pb had a catalytic effect on this reaction. Co and Mn shifted the nickel hydroxide redox potentials to more cathodic values. In contrast, Cd, Ce, Cr, Fe, La, Y, and Zn each shifted these redox potentials anodically. The coulombic efficiency of the oxidation‐reduction process was substantially lowered by Ce, Fe, and La.
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Citations
Cited by
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McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145
Solar-driven, highly sustained splitting of seawater into hydrogen and oxygen fuels
Kuang, Y., Kenney, M. J., Meng, Y., Hung, W.-H., Liu, Y., Huang, J. E., Prasanna, R., Li, P., Li, Y., Wang, L., et al. (2019) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1900556116 · Cited by 1,019
Recent Progress on Multimetal Oxide Catalysts for the Oxygen Evolution Reaction
Kim, J. S., Kim, B., Kim, H., & Kang, K. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702774 · Cited by 940
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Metadata
- Authors
- Corrigan, D. A., & Bendert, R. M.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1989-03-01
- Volume
- 136
- Issue
- 3
- Pages
- 723-728
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W1965586936
- Cited by
- 402
- References
- 0
- FWCI
- 4.25
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: Effect of Coprecipitated Metal Ions on the Electrochemistry of Nickel Hydroxide Thin Films: Cyclic Voltammetry in 1M KOH. https://app.cochat.ai/papers/10.1149/1.2096717
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- Corrigan, D. A., & Bendert, R. M. (1989). Effect of Coprecipitated Metal Ions on the Electrochemistry of Nickel Hydroxide Thin Films: Cyclic Voltammetry in 1M KOH. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2096717
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