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Electrocatalytic Electrodes for the Polysulfide Redox System
Open accessAbstract
Porous electrocatalytic electrodes for the polysulfide redox system, containing one of various metallic sulfides (especially of Co, Cu, Pb) are described. Emphasis is placed on their use as counterelectrodes in photoelectrochemical cells employing polysulfide electrolytes. Their activity is measured as a function of electrolyte temperature and composition. The ratio of S to S 2− , and through it the local redox potential of the solution, is shown to be an important factor controlling electrode activity. The short and long term stability of the electrodes, as cathodes, is discussed, and it is shown that, when used in conjunction with photoanodes, and may poison the photoelectrode surface, thereby reducing total cell efficiency.
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Citations
Cited by
Faber, M. S., & Jin, S. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01760a · Cited by 1,317
Characterization of nanostructured hybrid and organic solar cells by impedance spectroscopy
Fabregat-Santiago, F., Garcia-Belmonte, G., Mora-Seró, I., & Bisquert, J. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c0cp02249g · Cited by 1,206
PbS as a Highly Catalytic Counter Electrode for Polysulfide-Based Quantum Dot Solar Cells
Tachan, Z., Shalom, M., Hod, I., Rühle, S., Tirosh, S., & Zaban, A. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp112010m · Cited by 301
Faber, M. S., Park, K., Cabán-Acevedo, M., Santra, P. K., & Jin, S. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz400642e · Cited by 206
Metadata
- Authors
- Hodes, G., Manassen, J., & Cahen, D.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1980-03-01
- Volume
- 127
- Issue
- 3
- Pages
- 544-549
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2013010234
- Cited by
- 336
- References
- 0
- FWCI
- 7.82
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: Electrocatalytic Electrodes for the Polysulfide Redox System. https://app.cochat.ai/papers/10.1149/1.2129709
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- Hodes, G., Manassen, J., & Cahen, D. (1980). Electrocatalytic Electrodes for the Polysulfide Redox System. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2129709
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