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A Mechanistic Study of O 2 Reduction on Water Soluble Phthalocyanines Adsorbed on Graphite Electrodes
Open accessAbstract
Co and Fe tetrasulfonate phthalocyanines (M‐TSP), adsorbed at monolayer levels on graphite surfaces, have been found to have a pronounced catalytic effect on the reduction process in both acid and alkaline solutions. The kinetics have been examined with the rotating ring‐disk electrode technique. Co‐TSP promotes the reduction process via two electrons to give peroxide whereas Fe‐TSP promotes a four‐electron reduction to give water.
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Cited by
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Self-citationThe Role of Platinum in Proton Exchange Membrane Fuel Cells
Holton, O. T., & Stevenson, J. W. (2013) · Platinum Metals Review · doi:10.1595/147106713x671222 · Cited by 353
Morozan, A., Campidelli, S., Filoramo, A., Jousselme, B., & Palacin, S. (2011) · Carbon · doi:10.1016/j.carbon.2011.07.004 · Cited by 309
Chen, Z., Jiang, S., Kang, G., Nguyen, D., Schatz, G. C., & Van Duyne, R. P. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07979 · Cited by 171
He, P., Lu, J., Cha, C., Crouigneau, P., Lǵer, J. M., & Lamy, C. (1990) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/0022-0728(90)87431-i · Cited by 7
Metadata
- Authors
- Zagal, J., Bindra, P., & Yeager, E.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1980-07-01
- Volume
- 127
- Issue
- 7
- Pages
- 1506-1517
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2075573674
- Cited by
- 325
- References
- 0
- FWCI
- 17.26
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Zagal, J., Bindra, P., & Yeager, E. (1980). A Mechanistic Study of O 2 Reduction on Water Soluble Phthalocyanines Adsorbed on Graphite Electrodes. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2129940
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