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Model of Carbon Corrosion in PEM Fuel Cells
Abstract
This paper presents a mathematical model of the corrosion of carbon catalyst supports in polymer electrolyte membrane (PEM) fuel cells. The model describes how a maldistribution of hydrogen across the fuel electrode can induce both oxygen evolution and carbon corrosion on the positive electrode of the fuel cell in the fuel-starved region. Implications of this reverse-current mechanism are explored by simulating a cell with a nonuniform distribution of hydrogen along the fuel channel in both steady-state and transient operation.
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Citations
Cited by
Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation
Borup, R., Meyers, J., Pivovar, B., Kim, Y. S., Mukundan, R., Garland, N., Myers, D., Wilson, M., Garzon, F., Wood, D., et al. (2007) · Chemical Reviews · doi:10.1021/cr050182l · Cited by 3,402
Self-citationAnion-exchange membranes in electrochemical energy systems
Varcoe, J. R., Atanassov, P., Dekel, D. R., Herring, A. M., Hickner, M. A., Kohl, P. A., Kucernak, A. R., Mustain, W. E., Nijmeijer, K., Scott, K., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01303d · Cited by 2,051
Chen, F.-Y., Wu, Z.-Y., Adler, Z., & Wang, H. (2021) · Joule · doi:10.1016/j.joule.2021.05.005 · Cited by 1,284
A review of accelerated stress tests of MEA durability in PEM fuel cells
ZHANG, S., YUAN, X., WANG, H., MERIDA, W., ZHU, H., SHEN, J., WU, S., & ZHANG, J. (2009) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2008.10.012 · Cited by 525
Carbon as catalyst and support for electrochemical energy conversion
Trogadas, P., Fuller, T. F., & Strasser, P. (2014) · Carbon · doi:10.1016/j.carbon.2014.04.005 · Cited by 522
Metadata
- Authors
- Meyers, J. P., & Darling, R. M.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2006
- Volume
- 153
- Issue
- 8
- Pages
- A1432
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2034980493
- Cited by
- 430
- References
- 0
- FWCI
- 25.30
- Type
- journal article
- Language
- en
- Open access
- closed
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- Meyers, J. P., & Darling, R. M. (2006). Model of Carbon Corrosion in PEM Fuel Cells. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2203811
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.