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The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.

Crystalline MnO[sub 2] as Possible Alternatives to Amorphous Compounds in Electrochemical Supercapacitors

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Brousse, Thierry, Toupin, Mathieu, Dugas, Romain, Athouël, Laurence, Crosnier, Olivier, Bélanger, Daniel·2006·Journal of The Electrochemical Society

Abstract

Manganese dioxide compounds with various structures were synthesized and tested as "bulk" composite electrodes for electrochemical capacitors. The capacitance of the set of compounds having Brunauer–Emmett–Teller (BET) surface areas larger than reached a maximum value of about . The capacitance of all amorphous compounds (except one) is due to faradaic processes localized at the surface and subsurface regions of the electrode. Further increasing the surface area does not provide additional capacitance. The capacitance of the crystallized materials is clearly dependent upon the crystalline structure, especially with the size of the tunnels able to provide limited cations intercalation. Thus, the 2D structure of birnessite materials gives an advantage to obtain relatively high capacitance values considering their moderate BET surface area . 1D tunnel structure such as γ- or is characterized by only a pseudofaradic surface capacitance and therefore relies on the BET surface area of the crystalline materials. 3D tunnel structure such as shows some intermediate behavior between birnessite and 1D tunnel structures.

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Metadata

Authors
Brousse, T., Toupin, M., Dugas, R., Athouël, L., Crosnier, O., & Bélanger, D.
Venue
Journal of The Electrochemical Society
Published
2006
Volume
153
Issue
12
Pages
A2171
ISSN
0013-4651 (ISSN-L)
OpenAlex
W2118034597
Cited by
710
References
37
FWCI
10.93
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Crystalline MnO[sub 2] as Possible Alternatives to Amorphous Compounds in Electrochemical Supercapacitors. https://app.cochat.ai/papers/10.1149/1.2352197
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Brousse, T., Toupin, M., Dugas, R., Athouël, L., Crosnier, O., & Bélanger, D. (2006). Crystalline MnO[sub 2] as Possible Alternatives to Amorphous Compounds in Electrochemical Supercapacitors. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2352197

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