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Conduction Characteristics of the Lithium Iodide-Aluminum Oxide Solid Electrolytes
Abstract
The conduction characteristics of the polycrystalline lithium iodide containing aluminum oxide were studied. It was found that the incorporation of aluminum oxide substantially increased the conductivity of lithium iodide. Lithium iodide containing 33–45 mole per cent (m/o) aluminum oxide exhibited conductivities in the order of 10 −5 ohm −1 cm −1 at 25° ± 2°C. Inasmuch as no substantial amount of aluminum oxide was found soluble in the lithium iodide under the experimental conditions, the increase in conductivity could not be explained by the classical doping mechanism. The electronic conductivity of the lithium iodide‐aluminum oxide solid was negligible compared to the ionic conductivity. Therefore, it is suitable as a solid electrolyte in solid‐state battery systems.
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Cited by
Applications of hybrid organic–inorganic nanocomposites
Sanchez, C., Julián, B., Belleville, P., & Popall, M. (2005) · Journal of Materials Chemistry · doi:10.1039/b509097k · Cited by 2,636
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
Suo, L., Hu, Y.-S., Li, H., Armand, M., & Chen, L. (2013) · Nature Communications · doi:10.1038/ncomms2513 · Cited by 2,314
Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries
Wang, A., Kadam, S., Li, H., Shi, S., & Qi, Y. (2018) · npj Computational Materials · doi:10.1038/s41524-018-0064-0 · Cited by 1,639
Physics of inhomogeneous inorganic materials
Nan, C.-W. (1993) · Progress in Materials Science · doi:10.1016/0079-6425(93)90004-5 · Cited by 1,050
Progress of enhancing the safety of lithium ion battery from the electrolyte aspect
Wang, Q., Jiang, L., Yu, Y., & Sun, J. (2019) · Nano Energy · doi:10.1016/j.nanoen.2018.10.035 · Cited by 915
Metadata
- Authors
- Liang, C. C.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1973
- Volume
- 120
- Issue
- 10
- Pages
- 1289
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2171795534
- Cited by
- 939
- References
- 0
- FWCI
- 2.73
- Type
- journal article
- Language
- en
- Open access
- closed
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