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The Solubility and Diffusivity of Oxygen in Electrolytic Solutions
Open accessAbstract
Measurements of the solubility of oxygen in sulfuric acid, phosphoric acid, and potassium hydroxide are reported, together with values of the diffusivity of oxygen in potassium hydroxide solutions at 25°C. It is shown that for the electrolyte concentrations commonly employed in fuel cells the solubility and diffusivity of oxygen may each be reduced to as little as 2% of their corresponding values for pure water.
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Cited by
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Paulus, U. A., Wokaun, A., Scherer, G. G., Schmidt, T. J., Stamenkovic, V., Radmilovic, V., Markovic, N. M., & Ross, P. N. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp013442l · Cited by 954
Scaling the gas transfer velocity and hydraulic geometry in streams and small rivers
Raymond, P. A., Zappa, C. J., Butman, D., Bott, T. L., Potter, J., Mulholland, P., Laursen, A. E., McDowell, W. H., & Newbold, D. (2012) · Limnology and Oceanography: Fluids and Environments · doi:10.1215/21573689-1597669 · Cited by 721
Acidic or Alkaline? Towards a New Perspective on the Efficiency of Water Electrolysis
Schalenbach, M., Tjarks, G., Carmo, M., Lueke, W., Mueller, M., & Stolten, D. (2016) · Journal of The Electrochemical Society · doi:10.1149/2.0271611jes · Cited by 359
Mass-Transfer Measurements by the Limiting-Current Technique
Selman, J. R., & Tobias, C. W. (1978) · Advances in Chemical Engineering · doi:10.1016/s0065-2377(08)60134-9 · Cited by 352
A Perspective on Low-Temperature Water Electrolysis – Challenges in Alkaline and Acidic Technology
Schalenbach, M., Zeradjanin, A. R., Kasian, O., Cherevko, S., & Mayrhofer, K. J. J. (2018) · International Journal of Electrochemical Science · doi:10.20964/2018.02.26 · Cited by 305
Metadata
- Authors
- Gubbins, K. E., & Walker, R. D.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1965
- Volume
- 112
- Issue
- 5
- Pages
- 469
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2007820097
- Cited by
- 268
- References
- 0
- FWCI
- 3.48
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Gubbins, K. E., & Walker, R. D. (1965). The Solubility and Diffusivity of Oxygen in Electrolytic Solutions. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2423575
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.